| 面向工业烟道气CO2捕获的基于廉价配体金属有机骨架材料的研究进展 | |
| Research progress on low-cost ligand-based metal-organic frameworks for carbon dioxide capture from industrial flue gas | |
| 摘要: 利用高效绿色材料捕获CO2有助于减少人为向大气中排放CO2。目前，面向工业烟道气CO2捕获的高性能金属有机骨架(MOF)材料的设计与合成研究已步入应用驱使的新阶段。研发和制备具有优越综合性能的CO2捕获MOF材料是一项重要挑战。本综述重点关注面向工业烟道气CO2捕获的基于廉价配体MOF材料的研究现状，总结并讨论了其结构、水/热/化学稳定性、吸附量与选择性、吸附能力受湿气的影响、多轮循环使用性、再生性及宏量制备等性能。 | |
| 关键词: 廉价配体 金属有机骨架 CO2捕获 综合性能 | |
| 基金项目: 国家自然科学基金(No.22271150)和南京大学配位化学国家重点实验室开放课题(No.SKLCC2408)资助。 | |
| Abstract: Using efficient and green materials to capture carbon dioxide will be beneficial to reducing artificial emissions of carbon dioxide into the atmosphere. The design and synthesis of high-performance metal-organic frameworks (MOFs) for capturing carbon dioxide from flue gas has entered a new stage driven by the application. Developing MOFs for carbon dioxide capture with superior comprehensive performance is challenging. This review focuses on the current research on such MOFs with low-cost ligands. Furthermore, their structures, water/thermal/chemical stability, adsorption capacity and selectivity, adsorption behaviors affected by moisture, multi-cycle usability, regeneration, and macroscopic preparation were discussed. | |
| Keywords: low-cost ligand metal-organic framework carbon dioxide capture general performance | |
| 投稿时间：2024-09-30 修订日期：2024-12-16 | |
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| 江梦珍,王倩,白俊峰.面向工业烟道气CO2捕获的基于廉价配体金属有机骨架材料的研究进展[J].无机化学学报,2025,41(1):1-13. | |
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