| 多孔骨架材料电催化合成小分子物质的进展 |
| Process of electrocatalytic synthesis of small molecule substances by porous framework materials |
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| 摘要: 小分子物质在日常生活和生产中突显出日渐重要的作用，例如可用作能源的无机小分子氢气、氧气、氨、烃和过氧化氢，在生物化工方面的有机小分子尿素、氨基酸等。目前小分子物质的工业合成技术仍然存在一些问题，例如大量使用贵金属催化剂、能源损耗严重等。相对于传统工艺，电催化合成具有催化剂成本低、环境友好和性能高效等优点。基于金属有机骨架(MOFs)、共价有机骨架(COFs)和多孔配位笼(PCCs)的多孔材料催化剂，由于其独特的形态、结构可调节性、高催化活性和优异的化学稳定性等特点而受到广泛关注。因此，未来研究电催化合成小分子物质的一个关键领域是开发多孔骨架材料作为合成小分子物质的电催化剂。本文总结了这些材料在电催化方面的应用。 |
| 关键词: 多孔骨架材料 小分子物质 电催化合成 |
| 基金项目: 国家自然科学基金(No.22071049，22371067)资助。 |
| Abstract: Small molecules, including inorganic compounds such as hydrogen, oxygen, ammonia, hydrocarbons, and hydrogen peroxide that can serve as energy sources, as well as organic compounds like urea and amino acids used in the biochemical industry, are assuming an increasingly pivotal role in daily life and production. The industrial synthesis of small molecule substances still faces challenges, such as the extensive utilization of precious metal catalysts and significant energy inefficiency. Electrochemical synthesis offers several advantages over traditional processes, including reduced catalyst costs, enhanced environmental sustainability, and superior performance. Porous material catalysts based on metal-organic frameworks (MOFs), covalent organic frameworks (COFs), and porous coordination cages (PCCs) have attracted extensive attention due to their unique morphology, adjustable structure, high catalytic activity, and excellent chemical stability. Therefore, a key area of future research on the electrocatalytic synthesis of small molecules lies in advancing porous framework materials as electrocatalysts for synthesizing small molecule substances. This review provides a comprehensive overview of the utilization of these materials in electrocatalysis. |
| Keywords: porous framework material small molecule substance electrocatalytic synthesis |
| 投稿时间：2024-07-31 修订日期：2024-10-24 |
| 摘要点击次数: 440 |
| 全文下载次数: 651 |
| 苏智芳,管宗杰,方煜.多孔骨架材料电催化合成小分子物质的进展[J].无机化学学报,2024,40(12):2373-2395. |
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