| 多组分二维共轭金属有机骨架的研究进展 |
| Research progress on multivariate two-dimensional conjugated metal-organic frameworks |
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| 摘要: 多组分二维共轭金属有机骨架(MTV 2D c-MOFs)是一类由多种有机配体和金属节点通过配位键周期性组装而成的新型多孔晶态材料，由于具有可预测的拓扑结构、可调的孔隙率、高电导率和高电催化活性等优点，受到了广泛关注。同时，利用多金属离子或有机配体之间的协同作用，可以有效调节材料的电化学活性和选择性，为制备新型的功能性更强的2D c-MOFs提供了新的思路和方向。在这篇短综述中，我们小结了近年来报道的具有多金属节点或有机配体构建的MTV 2D c-MOFs的研究进展，并对其设计策略(双组分和三组分)、骨架优势和面临的挑战做出了展望。 |
| 关键词: 多组分金属有机骨架 电导率 电催化 |
| 基金项目: 国家自然科学基金(No.51973153，22222108)和国家重点研发计划(No.2017YFA0207500)资助。 |
| Abstract: Multivariate two-dimensional conjugated metal-organic frameworks (MTV 2D c-MOFs) represent a novel class of porous crystalline materials constructed by coordinating multiple organic ligands and metal nodes. These advantages include predictable topology, tunable porosity, high conductivity, and high electrocatalytic activity, making them widely applicable in electrocatalysis, energy storage, and gas sensing. By leveraging the synergistic effects of multiple metal ions or organic ligands, the electrochemical activity and selectivity of MTV 2D c-MOFs can be efficiently optimized, resulting in superior conductivity and catalytic performance compared to traditional two-component 2D c-MOFs. In this mini-review, we first outline several common construction strategies for MTV 2D c-MOFs and provide a detailed comparison with two-component 2D c-MOFs. In addition, we discuss the promising application prospects of MTV 2D c-MOFs across various fields. Finally, we address the current challenges hindering the development of MTV 2D c-MOFs, highlighting directions for future research and improvement. |
| Keywords: multivariate metal-organic frameworks electrical conductivity electrocatalysis |
| 投稿时间：2024-05-27 修订日期：2024-08-22 |
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| 霍然,张兆辉,苏熹,陈龙.多组分二维共轭金属有机骨架的研究进展[J].无机化学学报,2024,40(11):2063-2074. |
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