| 基于氟硅烷改性UIO-66-OH的疏水金属有机骨架材料的制备及在灰岩类石质文物保护中的应用 |
| Hydrophobic metal-organic framework material based on fluorosilane-modified UIO-66-OH: Preparation and application in the conservation of limestone cultural relics |
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| 摘要: 疏水材料的研制一直是石质文物保护工作中的难点问题。本工作制备了一种新型疏水金属有机骨架（MOF）材料，即采用氟硅烷修饰含有2-羟基对苯二甲酸桥联配体的Zr-MOF以获得UIO-O-FS材料，并对材料进行了FTIR、X射线衍射、N2吸附-脱附、热重、扫描电镜和透射电镜等表征分析以及抗侵蚀试验。试验结果表明，该材料具有良好的疏水性、固结性、耐酸性和耐盐性，是一种新型石质文物保护材料。 |
| 关键词: 金属有机骨架 UIO-66-OH 疏水 合成后改性 灰岩类石质文物保护 |
| 基金项目: 国家自然科学基金（No.51279073）和河南省高等学校重点科研项目（No.22B150010）资助。 |
| Abstract: The development of hydrophobic materials has always been a difficult issue in the protection of stone cultural relics. In this work, a new hydrophobic metal-organic framework material was synthesized by modifying the Zr-based MOFs containing 2-hydroxyterephthalic acid linkers with fluorosilane to obtain UIO-O-FS material, and characterization tests such as FTIR, X-ray diffraction, N2 adsorption-desorption, thermogravimetry, scanning electron microscope, and transmission electron microscope, as well as erosion resistance tests, were carried out on the material. Based on the results, the material possesses good hydrophobicity, consolidation ability, acid resistance, and salt resistance, and is a new type of stone heritage conservation material. |
| Keywords: metal-organic framework UIO-66-OH hydrophobic post-synthetic modification conservation of limestone heritage |
| 投稿时间：2022-12-25 修订日期：2023-06-09 |
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| 左天悦,张拦,王鸿毅,丁梧秀.基于氟硅烷改性UIO-66-OH的疏水金属有机骨架材料的制备及在灰岩类石质文物保护中的应用[J].无机化学学报,2023,39(9):1817-1831. |
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