氧-硼共修饰多壁碳纳米管载铂催化剂的制备及氧还原活性 |
Preparation of platinum catalysts supported on oxygen-boron co-modification multi-wall carbon nanotubes and their oxygen reducing activity |
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摘要: 采用一种简便的方法,合成了氧-硼共修饰的多壁碳纳米管材料,以此为载体制备的铂基催化剂具有更小的铂粒径、更高的电化学表面积(40 m2·gPt-1)和更高的氧还原活性(0.3 A·mgPt-1)。氧、硼在提高碳纳米管的载体分散性、控制铂颗粒的均匀性和粒径、促进氧还原反应的氧吸附/解离方面发挥着重要的作用。 |
关键词: 催化剂 碳纳米管 铂 硼 氧还原活性 |
基金项目: 南通市应用基础研究基金(No.JC2021109)资助 |
Abstract: We synthesized an oxygen-boron co-decorated multi-walled carbon nanotube material by a simple method. After that, it was used as a carrier to prepare platinum-based catalysts and carried out a variety of characterizations. The results indicated that the platinum particles supported on this carrier showed smaller particle size, higher electrochemical surface area (40 m2·gPt-1), and higher oxygen reduction activity (0.3 A·mgPt-1). Predictably, boron and oxygen play an important role in improving the dispersion of carbon nanotubes, controlling the uniformity and size of platinum particles, and promoting oxygen adsorption/dissociation in the oxygen reduction reaction. |
Keywords: catalyst carbon nanotubes platinum boron oxygen-reducing activity |
投稿时间:2022-07-22 修订日期:2022-10-21 |
摘要点击次数: 1892 |
全文下载次数: 1074 |
薛盛鼎,顾军,韩梦飞,祝苏君,于涛.氧-硼共修饰多壁碳纳米管载铂催化剂的制备及氧还原活性[J].无机化学学报,2023,39(2):281-290. |
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