| 镧掺杂锡酸钡/多壁碳纳米管改性隔膜的制备及其在锂硫电池中的应用 | |
| La-Doped BaSnO3/Multi-walled Carbon Nanotube Modified Separator: Synthesis and Application in Lithium-Sulfur Battery | |
| 摘要: 通过将共沉淀法制备的钙钛矿型氧化物镧掺杂锡酸钡(LBSO)与多壁碳纳米管(MCNT)混合均匀，制成浆料，并利用刮涂法将其涂布在商业隔膜Celgard 2500(PP)表面构筑阻挡层，获得改性隔膜(LBSO/MCNT/PP)。基于该改性隔膜的锂硫电池在0.1C下具有高达1 433 mAh·g-1的初始放电比容量，1C时300次循环后每圈容量衰减率为0.114%；当电流密度提高到3C时，仍具有764 mAh·g-1的放电比容量，表现出优良的倍率性能和循环稳定性，这主要是由于该阻挡层能够有效抑制多硫化物的穿梭。 | |
| 关键词: 锂电池 高储能 镧掺杂锡酸钡 穿梭效应 阻挡层 | |
| 基金项目: 国家自然科学基金(No.51972070、52062004)、贵州省科技计划项目重点类型(黔科合基础[2020]1Z042)、贵州省科技支撑项目(黔科合支撑[2021]一般317)、贵州大学培育项目(贵大培育[2019]01号)和贵州省研究生科研基金立项课题(黔教合YJSCXJH[2020]028)资助。 | |
| Abstract: Herein, an interlayer was constructed on the commercial separator Celgard 2500 (PP) by doctor blade coating a mixture slurry of perovskite oxide lanthanum doped barium stannate (LBSO) that was prepared by coprecipitation method and multi-walled carbon nanotubes (MCNT). The as-obtained modified separator was named LBSO/MCNT/PP. The lithium-sulfur battery using the modified separator delivered an initial discharge specific capacity up to 1 433 mAh·g-1 at 0.1C and a capacity decay rate of 0.114% per cycle over 300 cycles at 1C. As the current density was increased to a 3C rate, a discharge specific capacity of 764 mAh·g-1 can still be maintained, showing excellent rate capability and cycling stability, which is ascribed to the effective inhibition of the interlayer towards the shuttle of polysulfides. | |
| Keywords: lithium batteries high energy storage lanthanum doped barium stannate shuttle effect interlayer | |
| 投稿时间：2022-02-01 修订日期：2022-04-29 | |
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| 朱绍宽,宋娅,龙翔,欧阳全胜,邵姣婧,石斌.镧掺杂锡酸钡/多壁碳纳米管改性隔膜的制备及其在锂硫电池中的应用[J].无机化学学报,2022,38(7):1433-1440. | |
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