| 1，1'-二羟基-5，5'-联四唑的镧系金属配合物的合成、表征及热行为 | |
| Synthesis, Characterization and Thermal Behavior of Lanthanide Metal Complexes Based on 1H,1'H-5,5'-Bitetrazole-1,1'-diolate | |
| 摘要: 以1，1'-二羟基-5，5'-联四唑（H2BTO）为配体，镧系金属离子作为金属中心，采用溶剂热法制备了5种金属配合物：[La2（BTO）3（H2O）8]·2H2O （1）、[Ce2（BTO）3（H2O）8]·2H2O （2）、[Pr2（BTO）3（H2O）8]·2H2O （3）、[Sm2（BTO）3（H2O）8]·2H2O （4）和[Nd2（BTO）3（DMF）4]·6H2O （5）。通过单晶X射线衍射和元素分析对5种配合物的结构进行了表征。结果表明，5种配合物均属于单斜晶系，P21/n空间群。利用差示扫描量热法研究了配合物1~4的热稳定性，采用Kissinger法和Ozawa法分别计算了其热分解动力学参数。 | |
| 关键词: 含能材料 镧系金属配合物 1，1'-二羟基-5，5'-联四唑 晶体结构 热分析 | |
| 基金项目: 国家自然科学基金（No.21875192）、四川省杰出青年科技人才计划（No.19JCQN0085）、四川省科技厅应用基础研究项目（No.2019YJ0355）和环境友好能源材料国家重点实验室开放基金（No.20fksy16）资助。 | |
| Abstract: Five lanthanide metal complexes,[La2(BTO)3(H2O)8]·2H2O (1),[Ce2(BTO)3(H2O)8]·2H2O (2),[Pr2(BTO)3(H2O)8]·2H2O (3),[Sm2(BTO)3(H2O)8]·2H2O (4) and[Nd2(BTO)3(DMF)4]·6H2O (5), were synthesized by solvothermal method with 1H,1'H-5,5'-bitetrazole-1,1'-diolate (H2BTO) as ligand and lanthanide metal ions as metal centers. The structures of five complexes were characterized by single crystal X-ray diffraction and elemental analysis. The results show that all the complexes belong to monoclinic system, P21/n space group. The thermal stability of complexes 1~4 was investigated by differential scanning calorimetry. And their kinetic parameters of thermal decomposition were calculated by Kissinger method and Ozawa method, respectively. | |
| Keywords: energetic materials lanthanide metal complexes 1H,1'H-5,5'-bitetrazole-1,1'-diolate crystal structure thermal analysis | |
| 投稿时间：2021-04-12 修订日期：2021-05-13 | |
| 摘要点击次数: 1328 | |
| 全文下载次数: 1101 | |
| 罗利琼,王从军,沈娟,金波,彭汝芳.1，1'-二羟基-5，5'-联四唑的镧系金属配合物的合成、表征及热行为[J].无机化学学报,2021,37(9):1529-1535. | |
| 查看全文 查看/发表评论 下载PDF阅读器 | |
| Support information: 相关附件： file210174_支撑材料.docx | |
|
| |
|
| |
|
| |