用于高性能超级电容器的“三明治”结构Co9S8/NiTe/Ni的设计与合成 |
Design and Synthesis of Sandwich-like Co9S8/NiTe/Ni Composites for High-Performance Supercapacitors |
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摘要: 首先采用乙醇胺-氢氧化钾体系,实现了在泡沫镍表面原位生长NiTe活性物质层,随后以此为基体,通过复合Co9S8活性物质,构建出具有“三明治”结构、高容量、高循环稳定性的Co9S8/NiTe/Ni复合电极材料。该电极不仅在2 A·g-1电流密度下表现出1 890 F·g-1的比电容,而且在大电流密度下依然表现出优异的稳定性。 |
关键词: 超级电容器 "三明治"结构复合物 电化学 介孔材料 长循环稳定性 |
基金项目: 湖南省教育厅资助科研项目(No.18C0231)和湖南省自然科学基金(No.2018JJ3529)资助。 |
Abstract: The NiTe/Ni electrode was obtained in the mixed solvent of ethanolamine and KOH. Subsequently, the Co9S8/NiTe/Ni composite electrode with a sandwich-like structure was fabricated after the hydrothermal treatment in the aqueous solution of Co(NO3)2 and thiourea. The electrode not only exhibited an ultra-high specific capacity of 1 890 F·g-1 at a current density of 2 A·g-1, but also exhibited excellent cyclic stabilities at high current densities. |
Keywords: supercapacitor sandwich-like complexes electrochemistry mesoporous materials long-term cyclic stability |
投稿时间:2020-09-11 修订日期:2020-12-03 |
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陈鑫林,朱志平,吴宝鑫,陈曙光,周攀,贺浩.用于高性能超级电容器的“三明治”结构Co9S8/NiTe/Ni的设计与合成[J].无机化学学报,2021,37(2):295-304. |
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