| 不对称Salen配体的Ni(Ⅱ)/Cu(Ⅱ)/Mn(Ⅲ)配合物的合成及其晶体结构 | |
| Synthesis and Crystal Structure of Ni(Ⅱ)/Cu(Ⅱ)/Mn(Ⅲ) Complexes with Asymmetric Salen Ligand | |
| 摘要: 将（1R，2R）-环己二胺与2-羟基-1-萘甲醛和3，5-二叔丁基水杨醛反应，得到非对称Salen配体H2L，然后将配体H2L与Ni（OAc）2·4H2O、Cu（OAc）2·H2O、Mn（OAc）2·4H2O进行配位反应，得到3个单核配合物[Ni（L）]·CH2Cl2（1），[Cu（L）]（2），[Mn（L）（Cl）]·CH2Cl2（3），分别采用1H NMR、FT-IR和元素分析对化合物进行了表征，并通过X射线单晶衍射技术测定了配体和3个配合物的晶体结构。配体H2L属于正交晶系，P212121空间群。配合物1属于单斜晶系，P21/c空间群，而配合物2和配合物1的结构相似。配合物3属于三斜晶系，P1空间群。 | |
| 关键词: 不对称Salen配体 配合物 合成 晶体结构 | |
| 基金项目: 贵州省科技计划项目（黔科合支撑[2019]2792号）和贵州省科技计划项目（黔科合平台人才[2018]5779-14）资助 | |
| Abstract: Reaction of (1R,2R)-diaminocyclohexane with 2-hydroxy-1-naphthaldehyde and 3,5-di-tert-butyl sali-cylaldehyde gave an asymmetric salen ligand H2L. Then H2L conducted the coordination reaction with Ni(OAc)2·4H2O, Cu(OAc)2·H2O and Mn(OAc)2·4H2O, and three mononuclear complex of[Ni(L)]·CH2Cl2 (1),[Cu(L)] (2) and[Mn(L)(Cl)]·CH2Cl2 (3) were obtained. The compounds were characterized by 1H NMR, FT-IR and elemental analysis respectively and the crystal structure of ligand and three complexes were measured through X-ray single crystal diffraction technology. The ligand H2L belongs to the orthorhombic system, P212121 space group. Complex 1 belongs to the monoclinic system, P21/c space group, and the structures of complex 2 and 1 are similar. Complex 3 belongs to the triclinic system, P1 space group. | |
| Keywords: asymmetric salen ligand complex synthesis crystal structure | |
| 投稿时间：2019-07-11 修订日期：2019-10-17 | |
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| 张奇龙,王家忠,杨小生,朱必学.不对称Salen配体的Ni(Ⅱ)/Cu(Ⅱ)/Mn(Ⅲ)配合物的合成及其晶体结构[J].无机化学学报,2020,36(1):132-138. | |
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