| 锆簇基纳米分子胶囊的合成、晶体结构和荧光性质 |
| Synthesis, Crystal Structures and Fluorescence Properties of Two Nanosized Zr-Based Molecular Capsules |
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| 摘要: 选取4，4'-联苯二甲酸（4，4'-H2BPDC）和2，6-萘二甲酸（2，6-H2NDC）分别与二氯二茂锆（Cp2ZrCl2）反应制备了2例结构新颖的锆基纳米分子胶囊[Cp3Zr3（μ3-O）（μ2-OH）3]2（BPDC）3Cl2·H2O（Zr-MC-1）和[Cp3Zr3（μ3-O）（μ2-OH）3]2（NDC）3Cl2·3H2O（Zr-MC-2）。这2个分子胶囊均由3个线性羧基配体桥联2个三核茂锆建筑单元构成。利用单晶X射线衍射、粉末X射线衍射、元素分析、红外光谱、热重分析和氮气吸附-脱附等手段对化合物进行了表征。此外，荧光光谱分析表明Zr-MC-1和Zr-MC-2分别为深蓝光和蓝光发射材料，其最大发射波长分别为404和456 nm。 |
| 关键词: 分子胶囊 晶体结构 羧酸配体 荧光光谱 |
| 基金项目: 国家自然科学基金（No.21801038，21471027，21671034），吉林省教育厅（No.JJKH20190271KJ），中国博士后基金资助项目（No.2018M630312，2019T120227）和中央高校基本科研专项资金（No.2412018QD003）资助 |
| Abstract: Two nanosized zirconium-based molecular capsules (Zr-MCs), namely[Cp3Zr3(μ3-O)(μ2-OH)3]2(BPDC)3Cl2 ·H2O (Zr-MC-1) and[Cp3Zr3(μ3-O)(μ2-OH)3]2(NDC)3Cl2·3H2O (Zr-MC-2), have been synthesized by reacting zirconocenedichloride (Cp2ZrCl2) with 4,4'-biphenyldicarboxylic acid (4,4'-H2BPDC) and 2,6-naphthalenedicar-boxylic acid (2,6-H2NDC), respectively, which are constructed by two trinuclear zirconocene building blocks and three linear carboxylate ligands. They were characterized by single-crystal X-ray diffraction, powder X-ray diffraction, elemental analysis, IR spectroscopy, thermogravimetric analysis and N2 adsorption-desorption tests. In addition, the fluorescence spectra indicate that Zr-MC-1 and Zr-MC-2 are deep-blue and blue emitting materials with emission peaks at 404 and 456 nm, respectively. |
| Keywords: molecular capsule crystal structure carboxylate ligand fluorescence spectroscopy |
| 投稿时间：2019-07-29 修订日期：2019-09-09 |
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| 陶艳丽,陈维超,王新龙,苏忠民.锆簇基纳米分子胶囊的合成、晶体结构和荧光性质[J].无机化学学报,2019,35(11):2108-2116. |
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