| 配合物(BenzMeIm)2[PtCl4]的合成与表征 |
| Synthesis and Characterization of Complex (BenzMeIm)2[PtCl4] |
| 作者 | 单位 | E-mail | | Mohamad Ali Hikmat | Department of Chemistry, College of Education, University of Salahaddin, Erbil, Iraq | hikmatmohamad@yahoo.com | | Mahmoud Jamal Azheen | Department of Chemistry, College of Education, University of Salahaddin, Erbil, Iraq | | | Gerber Thomas | Department of Chemistry, Nelson Mandela Metropolitan University, Port Elizabeth, South Africa | | | Hosten Eric | Department of Chemistry, Nelson Mandela Metropolitan University, Port Elizabeth, South Africa | |
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| 摘要: 通过离子液体氯化1-苄基-3-甲基咪唑（BenzMeIm-Cl）与PtCl2的反应，合成了配合物（BenzMeIm）2[PtCl4]，并用元素分析、红外光谱、紫外-可见光谱、1H NMR、13C NMR和单晶X射线衍射对其进行了表征。单晶X射线分析表明，配合物结构属于P21/c空间群，晶胞参数和结构解析参数为：a=0.981 80（5）nm，b=0.861 47（3）nm，c=0.144 332（7）nm，β=92.480（2）°，V=121.96（1）nm3，R1=0.014 4，wR2=0.038 8。 |
| 关键词: 氯化1-苄基-3-甲基咪唑 铂 配合物 晶体结构 |
| 基金项目: |
| Abstract: A complex of (BenzMeIm)2[PtCl4] was prepared by the reaction of 1-benzyl-3-methylimidazolium chloride (BenzMeIm-Cl) with PtCl2. The structure of the complex was characterized by single crystal X-ray analysis, and it crystallizes in the monoclinic P21/c space group, with a=0.981 80(5) nm, b=0.861 47(3) nm, c=0.144 332(7) nm, β=92.480(2)°, V=121.96(1) nm3, R1=0.014 4, wR2=0.038 8. |
| Keywords: 1-benzyl-3-methylimidazolium chloride Pt(Ⅱ) complex crystal structure |
| 投稿时间：2017-08-24 修订日期：2018-01-25 |
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| Mohamad Ali Hikmat,Mahmoud Jamal Azheen,Gerber Thomas,Hosten Eric.配合物(BenzMeIm)2[PtCl4]的合成与表征[J].无机化学学报,2018,34(4):728-732. |
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