| CuNPs@Cu(II)-AMTD金属有机凝胶复合材料的合成及其催化性能 | |
| Synthesis of CuNPs@Cu(II)-AMTD Metal-Organic Gel Composites with High Catalytic Activities | |
| 摘要: 在Cu（Ⅱ）-AMTD金属有机凝胶基质中原位生长铜纳米粒子，得到了CuNPs@Cu（Ⅱ）-AMTD纳米复合材料，并分别进行了IR，SPR，SEM，TEM，EDX，XPS等测试分析其形貌组成。所得材料对4-硝基酚还原为4-氨基酚以及其他硝基苯的还原反应显示了优良的催化性能。同时也讨论了催化反应的机理。 | |
| 关键词: 铜纳米粒子 金属有机凝胶 催化 硝基苯 | |
| 基金项目: 安徽省高校自然科学基金（No.KJ2017A314）、安徽省自然科学基金（No.1408085MKL21）和安徽师范大学研究生科研创新项目（No.2014yks047）资助。 | |
| Abstract: The CuNPs@Cu(Ⅱ)-AMTD metal-organic gel composites was prepared by in situ growth of copper nanoparticles within gel matrix. The resulting material has been characterized by IR, SPR, SEM, TEM, EDX and XPS. It was found that CuNPs@Cu(Ⅱ)-AMTD composites exhibit excellent catalytic activities on the reduction of 4-nitrophenol (4-NP) to 4-aminophenol (4-AP) and other nitroarenes by NaBH4 in aqueous solution. The mechanism of the catalytic reaction has also been discussed. | |
| Keywords: copper nanoparticle metal-organic gel catalytic nitroarene | |
| 投稿时间：2017-09-15 修订日期：2017-12-19 | |
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| 承勇,孙飞飞,封其春,周映华.CuNPs@Cu(II)-AMTD金属有机凝胶复合材料的合成及其催化性能[J].无机化学学报,2018,34(3):551-559. | |
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