| 2-乙酰吡嗪苯甲酰腙钴、锌和铜配合物的晶体结构及荧光性质 | |
| Co(Ⅱ)/Zn(Ⅱ)/Cu(Ⅱ) Complexes Containing Hydrazone Ligand Bearing Pyrazine Unit: Syntheses, Crystal Structures and Fluorescence Properties | |
| 摘要: 合成了配合物[Co（L）2]（1），[Zn（L）2]（2）和[Cu2（L）2Cl2]（3）（HL为2-乙酰吡嗪苯甲酰腙），并通过单晶衍射、元素分析及红外光谱表征了它们的结构。单晶衍射结果表明，配合物1和2同构，配体和金属的比例为2：1。每个配合物中，中心金属离子与来自2个阴离子配体L-的N2O电子供体配位，形成扭曲的八面体配位构型。在双核配合物3中，Cu（Ⅱ）离子与1个阴离子三齿酰腙配体、2个μ2桥联的氯离子配位，拥有扭曲的四方锥配位构型。此外还研究了配合物的荧光性质。 | |
| 关键词: 酰腙 配合物 吡嗪 晶体结构 荧光 | |
| 基金项目: 国家自然科学基金（No.21001040）、河南省科技厅基础与前沿项目（No.162300410011，162300410209）和河南省青年骨干教师项目（No.2014GGJS-045）资助。 | |
| Abstract: Three complexes, namely,[Co(L)2] (1),[Zn(L)2] (2) and[Cu2(L)2Cl2] (3) based on HL (HL=2-acetylpyrazine benzoylhydrazone) were synthesized and characterized by X-ray diffraction analyses. The results show that complexes 1 and 2 are isostructural, in which the molar ratio between the metal and the ligand is 1:2. The metal ion in each complex is surrounded by two enolizated ligands L- with N2O donor set, thus giving a distorted octahedral geometry. However, in the bi-nuclear complex 3, each Cu(Ⅱ) ion is coordinated with one monoanionic tridentate hydrazone ligand and two μ2-chloride anions, as[CuN2OCl2], indicating the coordination geometry is a distorted tetragonal pyramid. In addition, the luminescent properties of the complexes are discussed in detail. | |
| Keywords: acylhydrazone complex pyrazine crystal structure fluorescence | |
| 投稿时间：2017-05-31 修订日期：2017-10-09 | |
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| 侯旭锋,赵晓雷,张露,吴伟娜,王元.2-乙酰吡嗪苯甲酰腙钴、锌和铜配合物的晶体结构及荧光性质[J].无机化学学报,2018,34(1):201-205. | |
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