| 以正辛烷为稀释剂用不对称N-甲基-N-癸基烷基酰胺从硝酸中萃取U(Ⅵ) |
| Extraction of U(Ⅵ) from Nitric Acid Media with Asymmetric N-methyl-N-decyl Alkylamide in n-Octane |
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| 摘要: 高放废液中铀的提取具有重要意义。本文设计合成了系列结构相关的氮原子上具有甲基的不对称萃取剂,N-甲基-N-癸基辛酰胺(MDOA)、N-甲基-N-癸基癸酰胺(MDDA)和N-甲基-N-癸基月桂酰胺(MDDOA),详细研究了以正辛烷为稀释剂从硝酸介质中萃取U(Ⅵ)的热力学,考察了不同影响因素对萃取性能的影响,讨论了萃取剂结构与萃取性能的关系。 |
| 关键词: 铀 萃取 烷基酰胺 正辛烷 |
| 基金项目: 国家自然科学基金(No.21171069)资助项目。 |
| Abstract: The extraction of uranium from high level liquid waste is important. In this paper, a series of structural related asymmetric amide extractant bearing methyl on N atom, such as N-methyl-N-decyloctanamide (MDOA), N-methyl-N-decyl-decanamide (MDDA) and N-methyl-N-decyldodecanamide (MDDOA) was designed and synthesized. The extraction thermodynamics of U(Ⅵ) from nitric acid solutions with the aforementioned extractants in n-octane was investigated in detail and the various factors affected extraction properties were studied. |
| Keywords: uranium extraction alkylamide n-octane |
| 投稿时间：2015-06-09 修订日期：2015-12-26 |
| 摘要点击次数: 1722 |
| 全文下载次数: 1985 |
| 崔玉,李业新,杨小凤,杨红晓,陈国柱,孙国新.以正辛烷为稀释剂用不对称N-甲基-N-癸基烷基酰胺从硝酸中萃取U(Ⅵ)[J].无机化学学报,2016,32(2):211-215. |
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