| 4, 4'-二(1-咪唑基)苯硫醚及邻苯二甲酸构筑的两个配位聚合物的合成、晶体结构及荧光性质 |
| Syntheses, Crystal Structures and Fluorescent Properties of Two Coordination Polymers Based on 4,4'-Bis(imidazol-l-yl)diphenyl Thioether and Phthalic Acid |
|
| 摘要: 在温和的水热条件下,以4,4'-二(1-咪唑基)苯硫醚(BIDPT)和邻苯二甲酸(H2pht)为配体,合成了2个配位聚合物{[Zn(BIDPT)(pht)]2·2H2O·CH3OH}n(1)和{[Cd5(BIDPT)4(pht)5]·H2O}n(2),分别用X-射线单晶衍射、元素分析和IR等手段对它们进行了表征。结果表明,配位聚合物1和2为2D层状结构,配位聚合物1属于正交晶系,Pbcn空间群;配位聚合物2属于三斜晶系,P21/c空间群。此外还考察了1和2的热稳定性和固体荧光性质。 |
| 关键词: 配位聚合物 晶体结构 荧光 合成 |
| 基金项目: 国家重点基础研究发展计划(No.2010CB923303),国家自然科学基金(No.21371092),安徽高校省级自然科学研究基金(No.KJ2013B274)资助项目。 |
| Abstract: Two coordination polymers {[Zn(BIDPT)(pht)]2·2H2O·CH3OH}n (1) and {[Cd5(BIDPT)4(pht)5]·H2O}n (2) based on mixed-ligands, BIDPT (4,4'-bis(imidazol-l-yl)diphenyl thioether) and H2pht (phthalic acid), have been synthesized by mild hydrothermal method and characterized by single-crystal X-ray diffraction, elemental analysis, IRspectra. The results show that 1 and 2 feature 2D networks. Compound 1 crystallizes in the orthorhombic system, space group Pbcn. Compound 2 crystallizes in the monoclinic system of the P21/c space group. The thermal stability and luminescent properties of compounds 1 and 2 are also investigated. |
| Keywords: coordination polymer crystal structure photoluminescence synthesis |
| 投稿时间：2015-08-03 修订日期：2015-09-11 |
| 摘要点击次数: 1855 |
| 全文下载次数: 2014 |
| 徐涵,郑和根.4, 4'-二(1-咪唑基)苯硫醚及邻苯二甲酸构筑的两个配位聚合物的合成、晶体结构及荧光性质[J].无机化学学报,2015,31(11):2272-2278. |
| 查看全文 查看/发表评论 下载PDF阅读器 |
| Support information: |
|
|
|
|
|
|
