| 牺牲模板法制备空心结构钯纳米粒子/石墨烯复合体及其甲酸电氧化性能研究 |
| Synthesis of Hollow Palladium Nanoparticales Supported on Graphene by Template Sacrifice Method as the Enhanced Electrocatalyst for Formic Acid Oxidation |
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| 摘要: 通过PdCl42-与Co之间发生简单的置换反应, 在表面活性剂PVP的作用下, 成功地制备出由3 nm的Pd纳米粒子组成的空心结构Pd纳米球结构, 将其命名为Pd-NS.随后, 以石墨烯(GN)作为载体, 将Pd-NS负载在GN的表面制备了Pd-NS/GN催化剂.在甲酸电氧化催化反应中, Pd-NS/GN催化剂表现出较大的电化学比表面积、良好的电催化性能以及较高的稳定性. |
| 关键词: 空心结构 Pd纳米粒子 石墨烯 电催化性能 甲酸燃料电池 |
| 基金项目: 国家自然科学基金重点项目(No.210311),国家自然科学基金重大研究计划培育项目(No.91122018),教育部高等学校科技创新工程重大项目培育资金项目(No.708029),中国高等教育博士点专项科研基金(No.20112301110002)资助项目. |
| Abstract: An efficient synthetic strategy have been developed, which is based on the simple substitution reaction between PdCl42- and Co. Under the action of surfactant PVP, the hollow structure of Pd catalyst was prepared successfully. Subsequently, graphene was used as the support. After loading the Pd-NS on the surface of graphene, the Pd-NS/GN catalyst was prepared. For the electrooxidation of formic acid, Pd-NS/ GN catalyst showed a larger electrochemical specific surface area, good electrical catalytic performance and high stability. |
| Keywords: hollow structure Pd nanoparticales grapheme electro-catalytic property formic acid fuel cells |
| 投稿时间：2014-04-21 修订日期：2014-06-30 |
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| 田玫,王博.牺牲模板法制备空心结构钯纳米粒子/石墨烯复合体及其甲酸电氧化性能研究[J].无机化学学报,2014,30(12):2747-2752. |
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