| MoS2非贵金属电催化剂担载对p-InP光阴极分解水性能的影响 | |
| Effect of Non-Noble Electrocatalyst MoS2 Loading on Photoelectrochemical Property of an InP Photocathode for Water Splitting | |
| 摘要: 将MoS2电催化剂担载在InP光阴极表面，提升了InP光阴极光电化学分解水产氢性能，确定了最优的MoS2电催化剂担载电量为15mC·cm-2；在担载前后，开启电势由-100mV移动至120mV；在-0.35V vs RHE时，电流密度由15mA·cm-2提升至43mA·cm-2。另外，通过改变入射光强和加入电子牺牲剂的方法进一步研究了MoS2担载InP光阴极产氢反应的限制步骤为光生电子与空穴在InP表面的复合。 | |
| 关键词: 太阳能水分解 InP光阴极 MoS2助催化剂 | |
| 基金项目: 国家重点基础研究发展计划（973计划，2013CB632404，2014CB239303）、国家自然基金（No.51272101）、江苏省自然科学基金（No.BK20130053）资助项目。 | |
| Abstract: MoS2 as a co-catalyst was loaded on the surface of a p-InPphotocathode to improve the photoelectrochemical property. The optimum electrical quantity of MoS2 loading was 15 mC·cm-2. After the MoS2 loading, onset potential of an InPphotocathode was shifted from -100 mVto 120 mV, and current density was improved from 15 mA·cm-2 to 43 mA·cm-2 at-0.35 Vvs RHE. Moreover，the limit step of a MoS2/InPphotocathode for hydrogen evolution was investigated by controlling light intensity and adding electron sacrificial agent into the electrolyte. Recombination of the photogenerated electrons and holes was the limit step on a MoS2/InPphotocathode for hydrogen evolution. | |
| Keywords: solar water splitting an InP photocathode MoS2 co-catalysts | |
| 投稿时间：2014-04-14 修订日期：2014-05-28 | |
| 摘要点击次数: 2260 | |
| 全文下载次数: 3073 | |
| 袁野,罗文俊,邹志刚.MoS2非贵金属电催化剂担载对p-InP光阴极分解水性能的影响[J].无机化学学报,2014,30(9):2093-2098. | |
| 查看全文 查看/发表评论 下载PDF阅读器 | |
| Support information: | |
|
| |
|
| |
|
| |