| 3-氨基-1，4，5，6-四氢吡咯[3，4-c]吡唑构筑的钴(Ⅱ)、铜(Ⅱ)配合物的晶体结构 |
| Crystal, Structures of, Cobalt(Ⅱ) and, Copper(Ⅱ) Complexes with 3-Amino-1,4,5,6-tetrahydropyrrolo[3,4-c]pyrazole |
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| 摘要: 以3-氨基-1，4，5，6-四氢吡咯[3，4-c]吡唑(Athpp)为配体合成了2个金属配合物即CoCl4(Athpp)2·2H2O(1)和CuCl4(Athpp)2(2)。用红外、元素分析和X-射线单晶衍射等手段表征了晶体结构。配合物1结晶在P1空间群而配合物2结晶在P21/n空间群。金属中心均采取扭曲八面体构型。此外，还研究了配合物的固体荧光性质 |
| 关键词: 钴(Ⅱ)配合物 铜(Ⅱ)配合物 晶体结构 吡唑衍生物 |
| 基金项目: 国家自然科学基金(No.20801012)和江苏爱纳吉新能源科技有限公司(No.8507040091)资助项目。 |
| Abstract: Two compounds CoCl4(Athpp)2·2H2O (1) and CuCl4(Athpp)2 (2) were respectively obtained by the reactions of 3-amino-1,4,5,6-tetrahydropyrrolo[3,4-c]pyrazole (Athpp) with cobalt(Ⅱ) chlorine and copper(Ⅱ) chlorine. The compounds have been characterized by FT-IR, elemental analyses and crystal structures. The compound 1 crystallizes in P1 space group and the compound 2 crystallizes in P21/n space group. The central metals are adopt distorted octahedral geometry. In addition, the fluorescent spectroscopy of the compounds were studied in solid state at room temperature. |
| Keywords: cobalt(Ⅱ) compound copper(Ⅱ) compound crystal structure pyrazole derivative |
| 投稿时间：2013-10-08 修订日期：2013-11-17 |
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| 储兆晶,白晓光,王玉成,陈金梅,赵红.3-氨基-1，4，5，6-四氢吡咯[3，4-c]吡唑构筑的钴(Ⅱ)、铜(Ⅱ)配合物的晶体结构[J].无机化学学报,2014,30(4):945-951. |
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