| 高分子担载席夫碱及其Cr(Ⅲ)配合物：合成、表征、抗菌和抗真菌性能评价 |
| Polymer-Bound Schiff Bases and Their Cr(Ⅲ) Complexes：Synthesis, Characterization, Antibacterial and Antifungal Evaluation |
| 作者 | 单位 | E-mail | | Nartop Dilek | Department of Chemistry, Faculty of Arts and Science, Nevsehir University, Nevsehir 50300, Turkey | dileknartop@nevsehir.edu.tr | | Sarş Nursen | Department of Chemistry, Faculty of Science, Gazi University, Ankara 06500, Turkey | | | Öğütçü Hatice | Department of Biology, Faculty of Science and Arts, Ahi Evran University, Kş
rsehir, 40100, Turkey | |
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| 摘要: 用胺甲基树脂与5-氟-2-羟基苯甲醛，5-氟-3-氯-2-羟基苯甲醛，5-氟-3-甲基-2-羟基苯甲醛反应合成了3种新颖的高分子担载席夫碱和它们Cr(Ⅲ)配合物，并用元素分析、磁化率、IR、1H NMR、UV-Vis、TG/DTA对其进行了表征。就一些革兰氏阳性菌(芽孢杆菌属腊状芽孢杆菌(Bacillus cereus sp)，单核细胞增生李斯特菌4b(Listeria monocytogenes 4b)，藤黄微球菌(Micrococcus luteus)，金黄色葡萄球菌(Staphylococcus aureus)表皮葡萄球菌(Staphylococcus epidermis))和革兰氏阴性菌(布鲁氏菌(Brucella abortus)，大肠杆菌(Escherichia coli)，恶臭假单胞菌SP(Pseudomonas putida sp.)，痢疾志贺氏菌10(Shigella dysenteria type 10)，伤寒杆菌H(Salmonella typhi H)和酵母菌(念珠菌)(yeast(Candida albicans))用井扩散法对高分子担载席夫碱和它们Cr(Ⅲ)配合物的生物学活性进行了筛选。 |
| 关键词: 高分子担载席夫碱 5-氟-2-羟基苯甲醛 5-氟-3-氯-2-羟基苯甲醛 5-氟-3-甲基-2-羟基苯甲醛 Cr(Ⅲ)配合物 抗微生 |
| 基金项目: Supported by the Research Foundation of Nevsehir University(Turkey)(BAP 2010/17). |
| Abstract: Three novel polymer-bound Schiff bases and their Cr(Ⅲ) complexes were synthesized from the reaction of polystyrene-A-NH2 with 5-fluoro-2-hydroxybenzaldehyde/5-fluoro-3-chloro-2-hydroxybenzaldehyde/5-fluoro-3-methyl-2-hydroxybenzaldehyde and were characterized by elemental analysis, magnetic susceptibility, IR, 1H NMR, UV-Vis, TG/DTA analysis. The biological activities of synthesized compounds were screened against some gram-positive bacteria (Bacillus cereus sp., Listeria monocytogenes 4b, Micrococcus luteus, Staphylococcus aureus, Staphylococcus epidermis) with some gram-negative bacteria (Brucella abortus, Escherichia coli, Pseudomonas putida sp., Shigella dysenteria type 10, Salmonella typhi H) and yeast (Candida albicans) by the well-diffusion method. |
| Keywords: polymeric-Schiff bases polystyrene-A-NH2 5-fluoro-2-hydroxybenzaldehyde 5-fluoro-3-chloro-2-hydroxybenzaldehyde 5-fluoro-3-methyl-2-hydroxyaldehyde Cr(Ⅲ) complexes antimicrobial activities |
| 投稿时间：2013-08-14 修订日期：2013-11-13 |
| 摘要点击次数: 1208 |
| 全文下载次数: 1915 |
| Nartop Dilek,Sarş Nursen,Öğütçü Hatice.高分子担载席夫碱及其Cr(Ⅲ)配合物：合成、表征、抗菌和抗真菌性能评价[J].无机化学学报,2014,30(4):921-929. |
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