| 两种N-2-嘧啶基-4-氨基苯磺酰Co(Ⅱ)配合物的合成、晶体结构及电催化性能研究 | |
| Syntheses, Crystal Structures and Electrochemical Behaviors of Two Co(Ⅱ) Complexes with N-2-Pyrimidinyl-4-amino-benzenesulfonamides | |
| 摘要: 水热法合成两种新的Co(Ⅱ)化合物[Co(SD)2(2，2’-bpy)](1)和{[Co(SD)2(4，4’-bpy)]·4H2O}n(2)(SD=N-2-嘧啶基-4-氨基苯磺酰，2，2’-bpy=2，2’-联吡啶，4，4’-bpy=4，4’-联吡啶)，并通过元素分析、红外光谱、X射线粉末衍射、热重分析、循环伏安法进行结构和性能表征。单晶X-ray衍射分析表明化合物1是三斜晶系，空间群为P1；化合物2是单斜晶系，空间群为C2/c。电催化实验发现化合物1和2对H2O2、HCHO都具有良好的电催化活性。 | |
| 关键词: 磺胺嘧啶 Co(Ⅱ)配合物 晶体结构 电催化 | |
| 基金项目: 国家自然科学基金(No.20971075，61078055)；结构化学国家重点实验室基金(No.20110010)；浙江省自然科学基金(No.LY12B01005)；宁波大学王宽诚幸福基金资助项目。 | |
| Abstract: Two new Co(Ⅱ) complexes, [Co(SD)2(2,2'-bpy)] (1) and {[Co(SD)2(4,4'-bpy)]·4H2O}n (2) (SD=sulfadiazine, 2,2'-bpy=2,2'-bipyridine, 4,4'-bpy=4,4'-bipyridine) have been synthesized through hydrothermal reaction and characterized by elemental analysis, IR, powder X-ray diffraction (PXRD), thermogravimetric analysis (TGA) and cyclic voltammetry (CV). Single crystal X-ray analysis reveals that compound 1 crystallizes in the triclinic system, space group P1 and compound 2 crystallizes in monoclinic crystal system, space group C2/c. It is found that these two compounds have electrochemical response behaviors for H2O2 and HCHO. | |
| Keywords: sulfadiazine Co(Ⅱ) complexes crystal structures electrochemical behavior | |
| 投稿时间：2013-07-30 修订日期：2013-10-26 | |
| 摘要点击次数: 1808 | |
| 全文下载次数: 2497 | |
| 冉繁敏,赵亚云,赵秀华,张洁,潘建国,李星.两种N-2-嘧啶基-4-氨基苯磺酰Co(Ⅱ)配合物的合成、晶体结构及电催化性能研究[J].无机化学学报,2014,30(4):913-920. | |
| 查看全文 查看/发表评论 下载PDF阅读器 | |
| Support information: | |
|
| |
|
| |
|
| |