| 两个2,6-二氨基-3,5-二硝基吡嗪-1-氧化物含能配合物的合成、晶体结构及催化性能 |
| Synthesis, Crystal Structure and Catalytic Properties of Two Energetic Complexes Containing 2,6-Diamino-3,5-dinitropyrazine-1-oxide |
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| 摘要: 合成了2，6-二氨基-3，5-二硝基吡嗪-1-氧化物(LLM-105) 2种含能配合物[Cu4O2(C4N6O5H2)2(CH3COO)2(DMF)2]·DMF(1)((C4N6O5H2)2-为配体LLM-105失去2个H+)和[Co(C4N6O5H3)3]·7H2O(2)((C4N6O5H3)-为LLM-105失去1个H+)，用X射线单晶衍射法测定了其分子结构。配合物1属正交晶系，空间群为Pbca，配合物2属三斜晶系，空间群为R3。用DSC，TG-DTG技术对配体和2个配合物的热分解进行了研究。用Kissinger法和Ozawa-Doyle法对配合物热分解过程中放热峰的表观活化能进行了计算。同时研究了2种配合物对AP热分解催化效果的影响，结果表明，2种配合物使AP的高温分解峰温分别提前117.42和71.85 ℃，分解放热量增加1 916.97和1 433.76 J·g-1，对AP热分解具有非常显著的催化效果。 |
| 关键词: LLM-105 含能配合物 晶体结构 热分解 催化性能 |
| 基金项目: 中央高校基本科研业务费专项资金资助，No.NUST2011YBXM66 |
| Abstract: Two energetic complexes with 2,6-diamino-3,5-dinitropyrazine-1-oxide (LLM-105) [Cu4O2 (C4N6O5H2)2(CH3COO)2(DMF)2]·DMF(1)((C4N6O5H2)2-is obtained by losing two protons from LLM-105) and [Co(C4N6O5H3)3]·7H2O(2) ((C4N6O5H3)- is obtained by losing a proton from LLM-105) have been synthesized and structurally characterized using X-ray diffraction. The results reveal that complex 1 belongs to the orthorhombic system (space group Pbca) and complex 2 belongs to the trigonal system (space group R3). Thermal decomposition of LLM-105 and two complexes was examined by DSC and TG-DTG analyses. The kinetic parameters of the exothermic processes of two complexes were studied by the Kissingers and Ozawa-Doyles methods. DSC measurements show that two complexes have decreased the higher thermal decomposition temperature of AP by 117.42 and 71.85 ℃, increased the exothermic quantity of decomposition by 1 916.97 and 1 433.76 J·g-1 respectively, showing good catalytic effects on the thermal decomposition of AP. CCDC: 938305, LLM-105; 911164, 1; 911163, 2. |
| Keywords: LLM-105 energetic complex crystal structure thermal decomposition catalytic property |
| 投稿时间：2013-06-04 修订日期：2013-09-22 |
| 摘要点击次数: 1945 |
| 全文下载次数: 1964 |
| 刘进剑,刘祖亮,成健.两个2,6-二氨基-3,5-二硝基吡嗪-1-氧化物含能配合物的合成、晶体结构及催化性能[J].无机化学学报,2014,30(3):696-704. |
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