| 基于4-(4-咪唑基-亚甲基氨基)苯甲酸配体配合物的合成及结构 |
| Syntheses and Crystal Structures of Complexes Based on 4-[(1H-imidazol-4-yl)methylamino]benzoic Acid Ligand |
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| 摘要: 利用不同的方法由配体4-(4-咪唑基-亚甲基氨基)苯甲酸(H2L)和过渡金属盐反应合成了3个配合物[M(HL)2(H2O)2](M(Ⅱ)=Mn(Ⅱ)(1)，Cd(Ⅱ)(2)，Cu(Ⅱ)(3))，进行了X-射线单晶衍射等表征。晶体结构解析结果表明：配合物1~3都属于三斜晶系，P1空间群，分子之间通过丰富的氢键相互作用最终形成了三维超分子结构。并且研究了配合物的热稳定性和电化学性质。 |
| 关键词: 4-(4-咪唑基-亚甲基氨基)苯甲酸 配合物 氢键作用 性质 |
| 基金项目: 国家自然科学基金（No.21272118）资助项目。 |
| Abstract: Reactions of ligand 4-[(1H-imidazol-4-yl)methylamino]benzoic acid (H2L) with transition metal salts led to the formation of three complexes [M(HL)2(H2O)2](M(Ⅱ)=Mn(Ⅱ)(1), Cd(Ⅱ)(2), Cu(Ⅱ)(3)) under different conditions. The single crystal X-ray diffraction analyses revealed that three complexes crystallized in the same triclinic space group P1 are isomorphous and isostructural, and the molecules are further connected by hydrogen bonds interactions resulting in formation of 3D structures. Thermal stability and electrochemistry properties of complexes were also investigated. CCDC: 945340, 1; 945338, 2; 945339, 3. |
| Keywords: 4-[(1H-imidazol-4-yl)methylamino]benzoic acid complex hydrgen bonding interaction properties |
| 投稿时间：2013-07-19 修订日期：2013-08-27 |
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| 徐静,陈敏东.基于4-(4-咪唑基-亚甲基氨基)苯甲酸配体配合物的合成及结构[J].无机化学学报,2013,29(12):2666-2672. |
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