| 以4’-羟基-联苯-4-羧酸和1,3-二(4-吡啶基)丙烷构筑的一维锌配位聚合物的晶体结构与荧光性质 |
| Synthesis, Structure and Luminescence of a 1D Zinc(Ⅱ) Coordination Polymer Constructed from 4’-Hydroxyl-biphenyl-4-carboxylate and 1,3-Bis(4-pyridyl)propane Ligands |
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| 摘要: 水热条件下采用Zn(NO3)2·6H2O,4'-羟基-联苯-4-羧酸和1,3-二(4-吡啶基)丙烷作为反应物合成出一个新的一维锌金属配位聚合物{[Zn(Hhbc)2(bpp)]·H2O}n (1)(Hhbc=4'-羟基-联苯-4-羧酸,bpp=1,3-二(4-吡啶基)丙烷),并分别用元素分析、红外光谱、差热分析、X-射线粉末衍射和X-射线单晶衍射等表征了该结构。晶体结构分析结果表明:化合物1为一维链状锌(Ⅱ)配位聚合物,通过分子间的O-H…O氢键作用,一维链进一步被连接成二维超分子结构。荧光分析表明常温固态下配合物1发射蓝色荧光,荧光寿命为3.08 ns(480 nm)。 |
| 关键词: 锌(Ⅱ)配位聚合物 晶体结构 4’-羟基-联苯-4-羧酸 1,3-二(4-吡啶基)丙烷 荧光性质 |
| 基金项目: 齐齐哈尔大学青年教师科研启动基金(No．2011K-M07)资助项目。 |
| Abstract: A new 1D zinc(Ⅱ) coordination polymer {[Zn(Hhbc)2(bpp)]H2O}n (1) (Hhbc=4'-Hydroxyl-biphenyl-4-carboxylate, bpp=1,3-bis(4-pyridyl)propane) has been synthesized by hydrothermal method and characterized by elemental analysis, IR, TGA, powder X-ray diffraction and single-crystal X-ray diffraction. The carboxylate oxygens of two different Hhbc ligands connect one ZnⅡ ion in bidentate-chelating and monodentate coordinated modes to form mononuclear zinc building blocks, which are further linked into a 1D infinite chain through trans-bpp ligands. These chains are further linked into a 2D supramolecular network through water-hydroxyl tetramers involving the free water molecules and hydroxyl groups of Hhbc ligands. Furthermore, the luminescent property of complex 1 was investigated at room temperature. CCDC: 919045. |
| Keywords: zinc(Ⅱ) coordination polymer hydrothermal synthesis crystal structure luminescence |
| 投稿时间：2013-01-19 修订日期：2013-03-25 |
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| 刘道森,梁法库,王志武.以4’-羟基-联苯-4-羧酸和1,3-二(4-吡啶基)丙烷构筑的一维锌配位聚合物的晶体结构与荧光性质[J].无机化学学报,2013,29(9):2007-2012. |
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