| 3,4-吡啶二酸钡配合物的合成、结构、荧光和热稳定性研究 |
| Synthesis, Structure, Luminescest and Thermal Stable Properties of 3,4-Pyridinedicarboxylic Acid Barium Complex |
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| 摘要: BaCl2·2H2O和配体3,4-吡啶二酸在溶剂热条件下反应生成了配合物[Ba2(pdc)2(H2O)3]n (1)(H2pdc=3,4-吡啶二酸),用单晶X-射线、元素分析和FT-IR对生成的晶体进行了表征。Ba1和Ba2分别采取了八配位扭曲四方反棱柱和十配位的双帽四棱柱几何构型,整个pdc2-作为四齿桥联配体连结4个不同的Ba(Ⅱ)原子形成二维网结构,O-H…N氢键将二维网结合在一起形成三维结构。还研究了配合物1的荧光和热重性质。 |
| 关键词: Ba(Ⅱ)配合物 羧基 荧光性质 热重 |
| 基金项目: 安徽省自然科学基金(No.1208085MB31);安徽省应用化学重点建设学科基金(No.200802187C);安徽省化学工程与工艺教学团队 (No.20101035);滁州学院大学生科研项目(No.2012XS18,2012XS19)资助项目。 |
| Abstract: Solvothermal reaction of BaCl2·2H2O with 3,4-pyridinedicarboxylic acid afforded a new inorganic-organic hybrid framework,[Ba2(pdc)2(H2O)3]n (1) (H2pdc=3,4-pyridinedicarboxylic acid). This complex has been fully characterized by single crystal X-ray diffraction, elemental analysis, and IR spectrum. X-ray analysis shows that complex 1 features a two-dimensional network (2D). Ba1 takes eight-coordinated distorted square antiprism geometry. Ba2 takes ten-coordinate distorted dicapped square prism coordination geometry. The whole pdc2- anion connects four different Ba(Ⅱ) atoms, giving rise to a 2D network structure. The three-dimensional structure is formed by O-H…N hydrogen bonding interactions. Thermal stability and luminescent property of compound 1 have also been investigated. CCDC: 887479. |
| Keywords: Ba(Ⅱ) complex carboxylate group luminescent property thermogravimetry |
| 投稿时间：2012-07-23 修订日期：2013-05-04 |
| 摘要点击次数: 2013 |
| 全文下载次数: 2170 |
| 左锣,冯建华,郭莉,李会会,吴刚.3,4-吡啶二酸钡配合物的合成、结构、荧光和热稳定性研究[J].无机化学学报,2013,29(9):1979-1984. |
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