| 取代四甲基环戊二烯基钌羰基化合物的合成及结构 | |
| Synthesis and Structures of Substituted Tetramethylcyclopentadienyl Diruthenium Complexes | |
| 摘要: 将配体[C5Me4HR](R=cyclopentyl,cyclohexyl,nPr)分别与Ru3(CO)12在二甲苯中加热回流,合成了3个新的双核配合物[(η5-C5Me4R)Ru(CO)(μ-CO)]2(R=cyclopentyl(1),cyclohexyl(2),nPr(3))。利用红外光谱、元素分析、核磁共振氢谱对它们的结构进行了表征,用X-射线单晶衍射法测定了1和2的结构。 | |
| 关键词: 羰基钌 环戊二烯基 结构 X-射线单晶衍射 | |
| 基金项目: 河北省自然科学基金(No.B2008000150);河北师范大学重点基金(No.L2009Z06)资助项目。 | |
| Abstract: The ligands[C5Me4HR] (R=cyclopentyl,cyclohexyl,nPr) reacted with Ru3(CO)12 in refluxing xylene to give three new substituted tetramethylcyclopentadienyl diruthenium metal carbonyl complexes[(η5-C5Me4R)Ru(CO)(μ-CO)]2 (R=cyclopentyl (1),cyclohexyl (2),nPr (3)),respectively. The three new complexes were characterized by IR,elemental analysis and 1H NMR spectra. The crystal structure of complexes 1 and 2 was determined by X-ray single crystal diffraction. CCDC: 891140, 1; 837727, 2. | |
| Keywords: ruthenium carbonyl cyclopentadienyl structure X-ray single crystal diffraction | |
| 投稿时间：2012-09-11 修订日期：2013-02-26 | |
| 摘要点击次数: 1957 | |
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| 马志宏,王娜,郭凯明,林进,郑学忠.取代四甲基环戊二烯基钌羰基化合物的合成及结构[J].无机化学学报,2013,29(9):1882-1886. | |
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