| 两个三维超分子铅配位聚合物的水热合成及晶体结构 | |
| Hydrothermal Synthesis and Crystal Structure of Two Three-Dimensional Supramolecular Lead(Ⅱ) Coordination Polymers | |
| 摘要: 通过水热法合成了2个新的金属-有机配位聚合物[Pb(NA)L]n 1,[Pb(CH3COO)L]n·nH2O 2(H2NA=烟酸,L=2-(4-硝基苯酚基)-1H-咪唑[4,5-f][1,10]邻菲罗啉)。并对其进行了元素分析、红外光谱、热重和X-射线单晶衍射测定。这2个配合物通过氢键和π-π相互作用形成了三维超分子网状结构。此外还研究了配合物1和2的荧光性质。 | |
| 关键词: 水热合成 晶体结构 铅配合物 | |
| 基金项目: 吉林省教育厅科学技术研究(吉教科合字[2012]第358号)资助项目。 | |
| Abstract: Two new metal-organic coordination polymers [Pb(NA)L]n 1, [Pb(CH3COO)L]n·nH2O 2 (H2NA=nicotinic acid, L=2-(4-nitrophenol)-1H-imidazo[4,5-f][1,10]phenanthroline) have been hydrothermally synthesized and structurally characterized by elemental analysis, IR, TG and single-crystal X-ray diffraction. They are further extended into a three-dimensional supramolecular network structure through hydrogen-bonding and π-π interactions. Moreover, the luminesent property of 1 and 2 have been investigated in the solid state. CCDC: 931504, 1; 931505, 2. | |
| Keywords: hydrothermal synthesis crystal structure lead complex | |
| 投稿时间：2012-10-29 修订日期：2013-02-25 | |
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| 赵丽娜,陈琳,刘博,李秀梅,王庆伟.两个三维超分子铅配位聚合物的水热合成及晶体结构[J].无机化学学报,2013,29(6):1243-1248. | |
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