| 一个手性双核镍配合物的合成、结构和CD光谱 | |
| Synthesis, Structure and CD Spectra of Chiral Dinuclear Nickel(Ⅱ) Complex | |
| 摘要: Ni(ClO4)2·6H2O与香草醛和L-2-氨基-3-苯基-1-丙醇在三乙胺的存在下反应得到L-[Ni2(van)(Hvap)2(MeOH)2]ClO4·2.5MeOH·H2O (1)。通过元素分析、红外、热重分析和固体CD光谱对1的结构进行了表征,并通过X-射线单晶衍射确定其单晶结构。结果表明1属于单斜晶系,P21手性空间群,Z=1,2个镍离子被脱去质子的香草醛分子桥联成{Ni2O}双核结构。固体CD光谱证实了1的手性。 | |
| 关键词: 手性多核配合物 镍(Ⅱ)配合物 晶体结构 CD光谱 | |
| 基金项目: 广东省高等学校高层次人才(No.2011QY01)和国家自然科学基金(No.21001119)资助项目。 | |
| Abstract: L-[Ni2(van)(Hvap)2(MeOH)2]ClO4·2.5MeOH·H2O (1) was prepared via the reaction of Ni(ClO4)2·H2O with o-vanillin and L-2-amino-3-phenyl-1-propanol in the presence of triethylamine. The structure of 1 was characterized by elemental analysis, IR, TGA, solid-state CD spectra and single-crystal X-ray diffraction analyses. The X-ray diffraction analyses reveal that the complex crystallizes in the monoclinic chiral space group P21 with Z=1. Two nickel (Ⅱ) ions are bridged by the deprotonated o-vanillin molecule, forming a {Ni2O} dinuclear structure. The solid-state CD spectra comfirm the chiral nature of 1. CCDC: 928211. | |
| Keywords: chiral polynuclear complex nickel(Ⅱ) complex crystal structure CD spectra | |
| 投稿时间：2012-08-01 修订日期：2013-02-05 | |
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| 向华,姜隆,李焕勇,郑晓丹,黎彧.一个手性双核镍配合物的合成、结构和CD光谱[J].无机化学学报,2013,29(5):1084-1088. | |
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