聚乙二醇稳定的RuB纳米粒子催化苯选择加氢为环己烯的性能研究 |
Polyethylene Glycol Stabilized RuB Nanoparticles: an Effective Catalyst for Selective Hydrogenation of Benzene to Cyclohexene |
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摘要: PEG稳定的RuB纳米粒子对苯选择加氢制备环己烯显示出良好的催化性能,在不添加硫酸锌的条件下,该体系催化的苯选择性加氢中,环己烯收率高达29%。这一体系的高催化性能是由于PEG稳定的RuB纳米粒子,使催化剂表面的亲水性增强,提高了环己烯的选择性。 |
关键词: Ru 苯 环己烯 加氢 |
基金项目: |
Abstract: The Polyethylene Glycol(PEG)stabilized RuB nanoparticles showed an excellent catalytic performance for selective hydrogenation of benzene to cyclohexene. Without ZnSO4, a maximum cyclohexene yield of 29% was obtained. The good performance of this catalyst system is attributed to the great hydrophilic property of RuB nanoparticles caused by PEG. |
Keywords: ruthenium benzene cyclohexene hydrogenation |
投稿时间:2012-06-07 修订日期:2012-07-26 |
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张晔,付海燕,李瑞祥,陈华,李贤均.聚乙二醇稳定的RuB纳米粒子催化苯选择加氢为环己烯的性能研究[J].无机化学学报,2013,29(3):577-582. |
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