| 草酸根及对咪唑基苯甲酸根构筑的三重互穿镉(Ⅱ)配合聚合物的合成、结构与发光性能研究 |
| Synthesis, Crystal Structure and Photoluminescence Property of Three-Fold Interpenetrating Cd(II) Complex Constructed by Oxalic Acid and 4-(Imidazol-1-yl)benzoic Acid |
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| 摘要: 利用水热方法合成了一个新的由草酸和对咪唑基苯甲酸混合配体共同构筑的镉配合物[Cd(L)(C2O4)0.5(H2O)]n,并通过元素分析、红外光谱和X-射线单晶衍射方法确定了该化合物的晶体结构。结构分析表明该化合物属于单斜晶系，空间群P21/n, 晶胞参数a=1.167 60(14) nm，b=0.841 80(15) nm，c=1.246 90(15) nm，β=105.404(2)，V=1.1815(3) nm3，Z=4，R1=0.0312，wR2=0.063 1。标题化合物包含一个格子状的二维层结构，三组相同的二维层相互穿插而构筑了三重互穿的框架，同时研究了化合物的光致发光性能。 |
| 关键词: 草酸 对咪唑基苯甲酸 水热合成 晶体结构 三重互穿 |
| 基金项目: |
| Abstract: A Cd(Ⅱ) complex constructed by mixed ligands oxalic acid and HL, [Cd(L)(C2O4)0.5(H2O)]n(HL=4-(imidazol- 1-yl)benzoic acid), has been synthesized under hydrothermal conditions and characterized by elemental analyses, IR spectrum and single crystal X-ray diffraction. It crystallizes in the monoclinic system, space group P21/n, a=1.167 60(14) nm, b=0.841 80(15) nm, c=1.246 90(15) nm, β=105.404(2)°, V=1.181 5(3) nm3, Z=4, R1=0.031 2, wR2=0.063 1. The titled complex includes a grid-like 2D layer. Three sets of these 2D layers interpenetrate with each other to construct a three-fold interpenetrating structure. Furthermore, the photoluminescence property of the titled complex has also been studied. CCDC: 874995. |
| Keywords: oxalic acid 4-(imidazol-1-yl) benzoic acid hydrothermal synthesis three-fold interpenetrating |
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| 张艳萍,王莉丽,刘连利,田爱香,应 俊.草酸根及对咪唑基苯甲酸根构筑的三重互穿镉(Ⅱ)配合聚合物的合成、结构与发光性能研究[J].无机化学学报,2013,29(2):350-354. |
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