| 2，2′-联吡啶-3，3′-二羧酸锰(Ⅱ)配合物的合成、晶体结构及性能研究(英文) |
| Synthesis, Crystal Structure and Properties of a New Manganese (Ⅱ) Complex with 2,2′-Bipyridine-3,3′-dicarboxylic Acid as a Ligand |
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| 摘要: 以2，2′-联吡啶-3，3′-二羧酸(H2L)和1，10-邻菲啰啉(Phen)为配体合成了一个新的锰(Ⅱ)配合物[Mn(H2O)(L)(Phen)2]·(H2O)3。该配合物晶体属单斜晶系，空间群P21/c。在配合物中，中心锰(Ⅱ)离子的配位数是6，处于变形的八面体配位环境中。还测定了标题配合物的磁性，荧光和电化学性能，结果表明：在低温下，配合物有反铁磁性；当激发波长为656 nm时，配合物在682 nm附近有一个宽的荧光发射峰；在循环伏安过程中配合物的电子转移是准可逆的，对应的电极反应是Mn(Ⅲ)/Mn(Ⅱ)。 |
| 关键词: 锰(Ⅱ)配合物 2，2′-联吡啶-3，3′-二羧酸 晶体结构 磁性、 荧光和电化学性能 |
| 基金项目: |
| Abstract: A new Mn(Ⅱ) complex [Mn(H2O)(L)(Phen)2]·(H2O)3 (1) with 2,2′-bipyridine-3,3′-dicarboxylic acid (H2L) and 1,10-Phenanthroline (Phen) as ligands has been synthesized. Crystal data for 1 are as follows: monoclinic, space group P21/c. In 1, the central Mn(Ⅱ) ion is located in a distorted octahedral coordination environment. The magnetic, fluorescence and electrochemical properties of 1 are studied. The results show that 1 has weak antiferromagnetic property at low temperatures, and when the exciting radiation is set at 656 nm, 1 can give off one broad emission band at around 682 nm. The electron transfer is quasi reversible in the electrode reaction, corresponding to Mn(Ⅲ)/Mn(Ⅱ). CCDC: 874919. |
| Keywords: manganese(Ⅱ) complex 2,2′-bipyridine-3,3′-dicarboxylic acid crystal structure magnetic fluorescence and electrochemical properties |
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| 张少华,杨颖群,匡云飞.2，2′-联吡啶-3，3′-二羧酸锰(Ⅱ)配合物的合成、晶体结构及性能研究(英文)[J].无机化学学报,2013,29(1):138-142. |
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