| 烯唑醇铜和银配合物的水热合成与晶体结构 |
| Synthesis and Crystal Structures of Complexes of Copper, Silver Assembled by Diniconazole |
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| 摘要: 合成了2个新的烯唑醇铜和银配合物：[CuL4Cl2] (1),[AgL2]NO3 (2)(L=diniconazole).通过元素分析、红外光谱和X-ray单晶衍射对其结构进行了表征.结构分析表明,1属三斜晶系,P1 空间群,晶胞参数为a=0.882 3(7) nm,b=1.370 5(10) nm,c=1.516 4(11)nm,α=91.507(11)°,β=97.356(9)°,γ=107.683(9)°.2属单斜晶系,P21/c空间群,晶胞参数为a=1.229 2(3) nm,b=1.272 1(3) nm,c=2.431 7(5) nm,β=98.694(3)°.1和2都由分子间氢键连接成一维链结构. |
| 关键词: 铜配合物 银配合物 烯唑醇 水热合成 晶体结构 |
| 基金项目: 国家自然科学基金(No.30760021);江西省自然科学基金(No.0530016);江西省教育厅青年基金(No.GJ10421)资助项目. |
| Abstract: Two new complexes [CuL4Cl2] (1) and [AgL2]NO3 (2) (L=diniconazole) were synthesized by solvothermal condition and structurally characterized by element analysis, IR and single crystal X-ray diffraction. Complex 1 is the Triclinic system, space group P1 with a=0.882 3(7) nm, b=1.370 5(10) nm, c=1.516 4(11) nm, α=91.507(11)°, β=97.356(9)°, γ=107.683(9)°. Complex 2 belongs to the Monoclinic system, space group P21/c with a=1.229 2(3) nm, b=1.272 1(3) nm, c=2.431 7(5) nm, α=90°, β=98.694(3)°, γ=90°. 1 and 2 are linked into a one dimensional chain by intermolecular hydrogen bonds. CCDC: 805738, 1; 818240, 2. |
| Keywords: copper complex silver complex diniconazole hydrothermal synthesis crystal structure |
| 投稿时间：2012-04-12 修订日期：2012-07-15 |
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| 聂旭亮,熊辉,涂勇刚,黄长干.烯唑醇铜和银配合物的水热合成与晶体结构[J].无机化学学报,2012,28(12):2593-@. |
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