| 两个N，N′-二(4-甲氧基亚水杨基)丙烷-1，3-二胺的镍(Ⅱ)配合物的合成、晶体结构和热稳定性研究(英文) |
| Syntheses, Crystal Structures, and Thermal Stability of Two Nickel(Ⅱ) Complexes Derived from N，N′-Bis(4-methoxysalicylidene)propane-1,3-diamine |
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| 摘要: 通过利用相同的原料但不同的合成过程，本文制备了一个单核镍(Ⅱ)配合物[NiL(H2O)] (1)，和一个三核镍(Ⅱ)配合物[Ni3L2(μ-CH3COO)2] (2)，其中L是N，N′-二(4-甲氧基亚水杨基)丙烷-1，3-二胺(H2L)的二价阴离子。通过元素分析、红外光谱以及X-射线单晶衍射表征了这2个配合物的结构。本文还研究了这2个配合物的热稳定性。 |
| 关键词: 合成 晶体结构 镍(Ⅱ)配合物 席夫碱 热稳定性 |
| 基金项目: |
| Abstract: A mononuclear nickel(Ⅱ) complex [NiL(H2O)] (1), and a trinuclear nickel(Ⅱ) complex [Ni3L2(μ-CH3COO)2] (2), where L is the dianionic form of N，N′-bis(4-methoxysalicylidene)propane-1,3-diamine (H2L), were synthesized from the same starting materials but with different synthetic procedures. The complexes were characterized by elemental analyses, infrared spectroscopy, and X-ray single crystal determination. The thermal stability of the complexes was also studied. CCDC: 736566, 1; 736567, 2. |
| Keywords: synthesis crystal structure nickel(Ⅱ) complex Schiff base thermal stability |
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| 张吉才,芦 瑶,李晓辉,由忠录.两个N，N′-二(4-甲氧基亚水杨基)丙烷-1，3-二胺的镍(Ⅱ)配合物的合成、晶体结构和热稳定性研究(英文)[J].无机化学学报,2012,28(6):1259-1264. |
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