| VO(Ⅱ), Fe(Ⅱ), Co(Ⅱ), Ni(Ⅱ)和Cu(Ⅱ)的2，3-二(3，5-二甲基-1H-吡唑基)喹啉配合物的合成与表征(英文) |
| Synthesis and Characterization of VO(Ⅱ), Fe(Ⅱ), Co(Ⅱ), Ni(Ⅱ) and Cu(Ⅱ) Complexes of 2, 3-Bis(3, 5-dimethyl-1H-pyrazol-1-yl) Quinoxaline |
| 作者 | 单位 | | Sandhya Rani D | Department of Chemistry, University College of Science, Osmania University, Hyderabad-500007, Andhra Pradesh, India.
Denisco Chemicals Private Limited, Plot#D-24, Phase-I, IDA, JeedimetlaHyderabad-500055, Andhra Pradesh, India. | | Anantha Lakshmi P V | Department of Chemistry, University College of Science, Osmania University, Hyderabad-500007, Andhra Pradesh, India.
Department of Chemistry, University College for Women, Osmania University, Koti, Hyderabad-500001, Andhra Pradesh, India. | | Kamala Prasad V2 Jayatyaga Raju V | Department of Chemistry, University College of Science, Osmania University, Hyderabad-500007, Andhra Pradesh, India.
Departement of Chemistry, The University of Dodoma, P.O.box Number 259, Dodoma,Tanazania |
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| 摘要: 合成了VO(Ⅱ)，Fe(Ⅱ)，Co(Ⅱ)，Ni(Ⅱ)和Cu(Ⅱ)的2，3-二(3，5-二甲基-1H-吡唑基)喹啉配合物(BDMPQ)并用元素分析、电导、热分析、光谱和顺磁共振等技术对其表征。结果表明所有配合物均为八面体构型。BDMPQ起中性双二齿NN供体的作用并形成 多核配合物。 |
| 关键词: 金属配合物 2，3-二(3，5-二甲基-1H-吡唑基)喹啉 NN供体 多核配合物 |
| 基金项目: |
| Abstract: VO(Ⅱ), Fe(Ⅱ), Co(Ⅱ), Ni(Ⅱ) and Cu(Ⅱ) complexes of 2, 3-bis(dimethyl -1H-pyrazol-1-yl)quinoxaline (BDMPQ) have been synthesized and characterized by elemental analysis, conductance, thermal, spectral and ESR techniques. Octahedral geometries have been proposed for all the complexes. BDMPQ acts as a neutral bis-bidentate NN donor and forms polynuclear complexes. |
| Keywords: metal complexes 2, 3-bis(dimethyl-1H-pyrazol-1-yl)quinoxaline, NN donor, polynuclear |
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| Sandhya Rani D,Anantha Lakshmi P V,Kamala Prasad V2 Jayatyaga Raju V.VO(Ⅱ), Fe(Ⅱ), Co(Ⅱ), Ni(Ⅱ)和Cu(Ⅱ)的2，3-二(3，5-二甲基-1H-吡唑基)喹啉配合物的合成与表征(英文)[J].无机化学学报,2012,28(6):1245-1250. |
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