| PbS插层K2Ti4O9催化剂：制备及光催化制氢活性 |
| PbS Intercalated K2Ti4O9: Preparation and Photocatalytic Properties |
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| 摘要: 利用高温固相反应、离子交换、层间插入反应和硫化处理制备了PbS插层的K2Ti4O9催化剂。利用XRD、TEM、SEM、XRF、PL和紫外-可见漫反射光谱对催化剂进行了表征，考察了催化剂紫外光和可见光光催化制氢活性。结果表明，制备的PbS插层K2Ti4O9催化剂对可见光的吸收范围较宽，其吸收边界约为710 nm，在紫外光和可见光下3 h累积产氢量可达到115.46 mmol·gcat-1和0.92 mmol·gcat-1，与CdS插层K2Ti4O9催化剂相比具有更高的催化活性。 |
| 关键词: 插层复合 钛酸钾 PbS 光催化 制氢 |
| 基金项目: |
| Abstract: PbS intercalated K2Ti4O9 was prepared via high-temperature solid-state reaction, ion exchange, sulfuration process. The material was characterized by XRD, TEM, SEM, XRF, PL, and UV-Vis spectroscopy. The activity of the photocatalysis for hydrogen evolution was determined under UV light and visible light irradiation, respectively. The results reveal that PbS intercalated K2Ti4O9 catalyst has a wide absorption range for visible light, and the absorption edge is at 710 nm. The photocatalytic hydrogen production activity after irradiation for 3 h under UV light and visible light over PbS intercalated K2Ti4O9 is 115.46 mmol·gcat-1 and 0.92 mmol·gcat-1, respectively. The photocatalytic activity of the title material is higher than that of CdS intercalated layered K2Ti4O9. |
| Keywords: intercalation K2Ti4O9 PbS photocatalysis hydrogen production |
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| 摘要点击次数: 1931 |
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| 崔文权,李立业,刘艳飞,胡金山,梁英华.PbS插层K2Ti4O9催化剂：制备及光催化制氢活性[J].无机化学学报,2012,28(4):773-778. |
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