碳化法国梧桐絮制备碳微米管及作为超级电容器电极的研究 |
Preparation of Carbon Microtubes by Carbonizing the Fluff of Chinar Tree and Their Application as Supercapacitor Electrodes |
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摘要: 利用法国梧桐絮(花粉)的管状结构,通过简单的碳化处理制备了碳微米管。并用扫描电子显微镜、X-射线衍射光谱仪、拉曼光谱仪和X射线光电子能谱仪对碳微米管进行了详细分析。碳微米管的外径为20~30 μm,壁厚约为1 μm。其内外壁存在着许多微孔和介孔,BET比表面积为265 m2·g-1。碳微米管具有典型的电化学双电层电容性能,表现出优异的稳定性,展示了在超级电容器方面的应用潜力。 |
关键词: 碳微米管 梧桐絮 生物质 超级电容器 |
基金项目: |
Abstract: The fluff (flower pollen) of chinar tree was carbonized to prepare carbon microtubes (CMTs) due to their natural micro-tubular structure. The as-prepared CMTs were well characterized by scanning electron microscopy, X-ray diffraction, Raman spectroscopy and X-ray photoelectron spectroscopy. The outer diameters of CMTs are in the range of 20~30 μm and the wall thickness is about 1 μm. Many micro- and meso-pores exist in their outer and inner walls, and the Brunauer-Emmett-Teller (BET) surface area is 265 m2·g-1. The CMTs were demonstrated to show a typical characteristics of electrochemical double layer capacitance, indicating their potential in supercapacitors. |
Keywords: carbon microtubes chinar fluff biomass supercapacitors |
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马延文,熊传银,黄 雯,赵 进,李兴螯,范曲立,黄 维.碳化法国梧桐絮制备碳微米管及作为超级电容器电极的研究[J].无机化学学报,2012,28(3):546-550. |
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