| 混合型甘氨酸-N，N-双亚甲基膦酸-磷酸锆：合成、表征及插层 |
| Mixed Zirconium Glycine-N, N-Dimethylphosphonate-Phosphate: Synthesis, Characterization and Intercalation |
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| 摘要: 采用氢氟酸络合法，在nP/nZr=2.0条件下，以甘氨酸-N，N-双亚甲基膦酸(DMPG)和H3PO4为原料，按不同投料物质的量的比制备了2个α、γ-混合型甘氨酸-N，N-双亚甲基膦酸-磷酸锆层状主体化合物Zr(PO4)0.41(HPO4)0.043[(O3PCH2)2NCH2COOH]0.67·H2O(1)和Zr(PO4)0.21(HPO4)0.038[(O3PCH2)2NCH2COOH]0.82·2H2O(2)，用元素分析、X射线衍射、红外光谱、热分析、固体核磁磷谱等对化合物进行了表征，同时研究了与正丁胺客体分子的插层组装性能。 |
| 关键词: 功能材料 混合型甘氨酸-N，N-双亚甲基膦酸-磷酸锆 插层 正丁胺 |
| 基金项目: |
| Abstract: Two α、γ-mixed layered zirconium glycine-N，N-dimethylphosphonate phosphates, Zr(PO4)0.41(HPO4)0.043[(O3PCH2)2NCH2COOH]0.67H2O(1)and Zr(PO4)0.21(HPO4)0.038[(O3PCH2)2NCH2COOH]0.82·2H2O (2), were synthesized by the reaction of zirconium oxychloride with glycine-N，N-dimethylphosphonate and phosphonic acid on the basis of different feeding molar ratios in the presence of HF, and were characterized by XRD, IR, TG-DSC, elemental analysis and 31P MAS NMR. The intercalation behavior with n-butylamine was also studied. |
| Keywords: functional materials mixed zirconium glycine-N,N-dimethylphosphonate-phosphate intercalation, n-butylamine |
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| 杨新斌,傅相锴,曾仁权.混合型甘氨酸-N，N-双亚甲基膦酸-磷酸锆：合成、表征及插层[J].无机化学学报,2012,28(3):519-522. |
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