| 两个由2-(4′-氯-苯甲酰基)苯甲酸构筑的铜、锰配合物的合成及晶体结构(英文) |
| Synthesis and Crystal Structure of Two Complexes of Copper, Manganese Assembled by 2-(4′-Chlorine-benzoyl)-benzoic Acid |
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| 摘要: 通过水热法合成了2个新的配合物[Cu(cbba)2(im)2] (1)和{[Mn(cbba)2(bipy)(H2O)2]·bipy}n(2)(Hcbba=2-(4′-氯-苯甲酰基)苯甲酸，im=咪唑，bipy=4，4′-联吡啶)。并对其进行了元素分析、红外光谱、热重和X-射线单晶衍射测定。这2个配合物通过氢键或π-π相互作用形成了三维超分子网状结构。 |
| 关键词: 水热合成 晶体结构 铜配合物 锰配合物 |
| 基金项目: |
| Abstract: Two new complex [Cu(cbba)2(im)2] (1) and {[Mn(cbba)2(bipy)(H2O)2]·bipy}n(2) (Hcbba=2-(4′-chlorine-benzoyl)-benzoic acid, im=imidazole, bipy=4,4′-bipyridine) have been hydrothermally synthesized and structurally characterized by elemental analysis, IR spectrum, TG and single-crystal X-ray diffraction. They are further extended into a three-dimensional supramolecular network structure through hydrogen bonds and π-π interactions. CCDC: 834794, 1; 834795, 2. |
| Keywords: hydrothermal synthesis crystal structure copper complex manganese complex |
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| 牛艳玲,李秀梅,王立斌,王志涛.两个由2-(4′-氯-苯甲酰基)苯甲酸构筑的铜、锰配合物的合成及晶体结构(英文)[J].无机化学学报,2011,27(11):2298-2302. |
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