| 邻菲咯啉衍生物及苯四甲酸构筑的一维铁(Ⅱ)配位聚合物的合成及结构(英文) | |
| Synthesis and Structure of a One-Dimensional Fe(Ⅱ) Coordination Polymer Based on 1,10-Phenanthroline Derivative and 1,2,4,5-Benzenetetracarboxylate | |
| 摘要: 水热法合成了1个一维配位聚合物[Fe2L2(btc)(H2O)2]n(L为邻菲咯啉衍生物 (2-(2-chloro-6-fluorophenyl)-1H-imidazo[4,5-f][1,10]phenanthroline，btc为苯四甲酸根)，并对该化合物进行了元素分析、红外，热重和单晶X-射线表征。该化合物属于三斜晶系，空间群P1，晶胞参数a=0.756 11(5) nm，b=1.003 63(4) nm，c=1.482 79(9) nm，α=91.190(1)°，β=100.569(2)°，γ=106.966(1)°，V=1.054 68(10) nm3，Z=2，R=0.035 0，wR=0.094 5。在该化合物中，苯四甲酸连接着Fe(Ⅱ)原子形成一维链状结构，链与链之间又进一步地通过π-π相互作用形成二维层状超分子结构，氢键进一步地稳定了此层状结构。 | |
| 关键词: 1，2，4，5-苯四酸 配位聚合物 晶体结构 邻菲咯啉衍生物 | |
| 基金项目: | |
| Abstract: A complex [Fe2L2(btc)(H2O)2]n(btc=1,2,4,5-benzenetetracarboxylate and L=(2-(2-chloro-6-fluorophenyl)-1H-imidazo[4,5-f][1,10]phenanthroline) was synthesized by hydrothermal reaction and characterized by elemental analysis, IR, thermogravimetric analysis (TGA), and X-ray single crystal diffraction. The title complex crystallizes in triclinic with space group P1, a=0.756 11(5) nm, b=1.003 63(4) nm, c=1.482 79(9) nm, α=91.190(1)°, β=100.569(2)°, γ=106.966(1)°, V=1.054 68(10) nm3, Z=2, R=0.035 0, wR=0.094 5. The structure analysis shows that the complex exhibits a one-dimensional chain structure. The 2D supramolecular network is constructed through π-π interactions among neighboring chains. The 2D supramolecular network was further stabilized by the hydrogen bonds. CCDC: 834793. | |
| Keywords: 1,2,4,5-benzenetetracarboxylic acid coordination polymer crystal structure 1,10-phenanthroline derivative | |
| 摘要点击次数: 1484 | |
| 全文下载次数: 2008 | |
| 王秀艳,马 帅,赵丽娜,陈 妍.邻菲咯啉衍生物及苯四甲酸构筑的一维铁(Ⅱ)配位聚合物的合成及结构(英文)[J].无机化学学报,2011,27(11):2283-2286. | |
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