| 以吲哚乙酸及邻菲咯啉为配体的镉配合物的合成、结构、荧光性质与抑菌活性研究 |
| A New Cadmium Complex with Indole-3-acetic Acid and 1,10-Phenanthroline Ligands: Synthesis, Crystal Structure, Photoluminescence and Antibacterial Activity |
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| 摘要: 采用溶液培养法，在室温条件下合成了1种新颖的过渡金属配合物[Cd(IAA)2(phen)](HIAA=吲哚乙酸，phen=1，10-邻菲咯啉)，并通过元素分析、红外光谱、X射线单晶结构分析对该配合物进行了表征。结构分析表明：标题配合物属于单斜晶系，P21/c空间群。晶胞参数a=1.243 47(10) nm，b=1.232 32(10) nm，c=1.828 83(15) nm，β=106.298 0(10)°，V=2.689 8(4) nm3。在配合物中，中心金属Cd(Ⅱ)为六配位，处于扭曲的八面体几何构型。此外，我们对标题配合物进行了荧光性质和抑菌活性的研究。 |
| 关键词: 吲哚乙酸 镉配合物 溶液合成 晶体结构 荧光性质 抑菌活性 |
| 基金项目: |
| Abstract: One kind of new transitional metal complex [Cd(IAA)2(phen) (HIAA=indole-3-acetic acid, phen=1,10-phenanthroline) has been synthesized by employing the solution a preparation method at room temperature. It was characteristic by elemental analysis, IR spectroscopy, and single-crystal X-ray diffraction. The analysis of the structure reveals that the title complex belongs to monoclinic system, space group P21/c. The cell parameters are: a=1.243 47(10) nm, b=1.232 32(10) nm, c=1.828 83(15) nm, β=106.298 0(10)°, V=2.689 8(4) nm3 respectively. In the structure of the complex, the metal center Cd(Ⅱ) is six-coordinated, display a distorted octahedron geometry. Additional, photoluminescent property and antibacterial activity for the title complex have also been investigated. CCDC: 821766. |
| Keywords: indole-3-acetic acid cadmium complex crystal structure photoluminescence property antibacterial activity |
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| 白凤英,吕 晓,刘淑清,李晓天.以吲哚乙酸及邻菲咯啉为配体的镉配合物的合成、结构、荧光性质与抑菌活性研究[J].无机化学学报,2011,27(7):1261-1264. |
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