| 正丁胺对晶态层状苯乙烯基膦酸-磷酸氢锆的插层研究 | |
| Intercalation of n-Butylamine into Layered Crystalline Zirconium Phenylvinylphosphonate-Phosphate | |
| 摘要: 合成了晶态层状有机-无机多功能材料苯乙烯基膦酸-磷酸氢锆(α-ZPPVPA)，并研究了正丁胺(BA)对α-ZPPVPA的插层性能。用元素分析、XRD、IR、TG、SEM和TEM等分析方法对α-ZPPVPA及其插层化合物α-ZPPVPA-BA进行了结构表征和形貌分析。结果表明，正丁胺成功地插入了α-ZPPVPA层板之间，层间距为2.41 nm，正丁胺的插入使α-ZPPVPA的层间距(1.66 nm)增大了0.75 nm，插入的正丁胺在α-ZPPVPA中呈双分子层排列，且苯乙烯基侧链不饱和双键的存在不影响α-ZPPVPA与正丁胺的插层反应。 | |
| 关键词: 苯乙烯基膦酸-磷酸氢锆 层状化合物 插层 正丁胺 | |
| 基金项目: | |
| Abstract: Layered crystalline zirconium phenylvinylphosphonate-phosphate (α-ZPPVPA) was synthesized as organic-inorganic multifunctional material. The intercalation complex of n-butylamine (BA) into α-ZPPVPA was studied. α-ZPPVPA and its intercalation complex α-ZPPVPA-BA were characterized by elemental analysis, XRD, IR, TG, SEM and TEM. The results indicated that n-butylamines were successfully intercalated into α-ZPPVPA interlayer and the interlayer distance of α-ZPPVPA-BA was 0.75 nm larger than that of α-ZPPVPA (1.66 nm). The n-butylamines, which intercalated into α-ZPPVPA, formed bi-molecule layer. The existence of unsaturated double bonds has no influence on the intercalation reaction of n-butylamine into α-ZPPVPA. | |
| Keywords: zirconium phenylvinylphosphonate-phosphate layered compound intercalation n-butylamine | |
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| 张怀志,傅相锴,王长炜,罗云飞,贾紫永.正丁胺对晶态层状苯乙烯基膦酸-磷酸氢锆的插层研究[J].无机化学学报,2011,27(5):872-876. | |
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