| Abstract: The dinuclear copper(Ⅱ) macrocyclic complex has been synthesized by condensation between N,N′-dimethyl-N,N′-bis(3-formyl-5-chlorosalicylidene)ethylene diamine and 1,3-propanediamine in the presence of copper(Ⅱ). The complex was determined by X-ray diffractions single crystal structure analysis. The results indicates that the complex crystallizes in monoclinic, space group P21, Flack parameters(x) =0.06(2), with a=0.871 05(16) nm, b=0.957 78(18) nm, c=1.810 4(3) nm, β=100.761(18)°, V=1.483 8(5) nm3, Z=2, Dc=1.762 Mg·m-3, μ=1.85 mm-1, F(000)=796, and final R1=0.061, wR2=0.126, The crystal structure shows that the two copper(Ⅱ) ions in the phenol-based macrocyclic dinuclear complex, are coordinated with (Namine)2O2 and (Nimine)2O2 sites. Magnetic measurements reveal an antiferromagentic interaction in the complex. CCDC: 624712. |
