| Abstract: A novel coordination polymer based on manganese(Ⅱ) and bipyridyldicarboxylate ligand, {[Mn(bpdc)(H2O)2]·H2O·CH3OH}n(1) (H2bpdc=2,2′-bipyridyl-4,4′-dicarboxylic acid), has been prepared by hydrothermal method. The complex crystallizes in the monoclinic system, space group P21/n with a=0.761 87(15) nm, b=1.574 4(3) nm, c=1.362 2(3) nm, β=105.84(3)°, V=1 571.8(5) nm3, Dc=1.619g·cm-3, Z=4, R=0.031 8 and wR=0.082 9 (I>2σ(I)). Compound 1 has a grid structure extended with subunits binuclear manganese. The open channel constitute about 14.8% of the crystal volume and are occupied by the CH3OH and water solvent molecules. CCDC: 778527. |
