| 二维配合物[Cd3(HBTA)2(BIPA)3]n的水热合成、晶体结构和荧光性质研究(英文) |
| Hydrothermal Synthesis, Crystal Structure and Photoluminescence of a New Two-Dimensional Cadmium(Ⅱ) Complex [Cd3(HBTA)2(BIPA)3]n |
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| 摘要: |
| 关键词: 镉配合物 晶体结构 多酸配体 荧光性质 |
| 基金项目: |
| Abstract: The hydrothermal reactions of 5-bromoisophthalic acid (H2BIPA), benzotriazole (HBTA) with Cd(NO3)2·4H2O in basified solvent gave rise to a coordination polymer [Cd3(HBTA)2(BIPA)3]n(1), which has been characterized by elemental analysis, IR and single-crystal X-ray diffraction. Complex 1 presents a two-dimensional (2D) layer network containing the edge-sharing 1D -O-Cd-O chains through repetitions of the alternating arrangement of the Cd3(CO2)6 cluster and displays strong luminescent emission at room temperature. CCDC: 775284. |
| Keywords: cadmium(Ⅱ) complex crystal structure multicarboxylate ligand luminescence |
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| 摘要点击次数: 1550 |
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| 刘光祥,许玉勇,任小明.二维配合物[Cd3(HBTA)2(BIPA)3]n的水热合成、晶体结构和荧光性质研究(英文)[J].无机化学学报,2010,26(10):1885-1889. |
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