| 由MOPIP配体构筑的两种金属配合物的合成、表征及晶体结构(英文) |
| Synthesis, Characterization and Crystal Structure of Two Metal-Organic Complexes with MOPIP |
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| 摘要: 采用水热法由2种不同金属盐和MOPIP (MOPIP=2-(4-methoxyphenyl)-1H-imidazo[4，5-f][1，10] phenanthroline)配体合成了2种新型零维配合物[Cd(MOPIP)3(H2O)9]4n (1)和[Mn(MOPIP)3(H2O)6]2n (2)，并对其进行了元素分析、红外光谱表征、热失重和Ｘ射线单晶衍射测定。结果表明，每个金属中心离子与来自3个不同MOPIP分子上的6个氮原子进行配位，形成畸变的八面体构型。 |
| 关键词: 2-(4-甲氧基)-1氢-咪唑[4，5-f][1，10]邻菲咯啉 锰(Ⅱ) 镉(Ⅱ) |
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| Abstract: Two unusual zero-dimensional (0D) compounds, viz. [Cd(MOPIP)3(H2O)9]4n (1) and [Mn(MOPIP)3(H2O)6]2n (2), are synthesized by the combination of two different metallic salts and 2-(4-methoxyphenyl)-1H-imidazo[4,5-f][1,10] phenanthroline (MOPIP) ligand. The compounds have been hydrothermally synthesized and structurally characterized by elemental analysis, IR spectrum, TG and single-crystal X-ray diffraction. The results show that every metal ion is hexa-coordinated with six nitrogen atoms from three different MOPIP ligands in the crystal structure, showing a slightly distorted octahedral geometry. CCDC: 775844, 1; 775845, 2. |
| Keywords: 2-(4-methoxyphenyl)-1H-imidazo[4,5-f][1,10] phenanthroline Manganese(Ⅱ) Cadmium(Ⅱ) |
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| 黄艳菊,倪 良,杜 刚,崔运成,张文莉,王 蕾,郝向荣.由MOPIP配体构筑的两种金属配合物的合成、表征及晶体结构(英文)[J].无机化学学报,2010,26(7):1269-1273. |
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