| 二重穿插锰配合物Mn2(ADB)2(DMSO)4DMSO的溶剂热合成和结构研究 |
| Solvothermal Synthesis and Crystal Structure of a Two Interpenetrating Mn(Ⅱ) Complex: Mn2(ADB)2(DMSO)4·DMSO |
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| 摘要: |
| 关键词: 锰(Ⅱ)配位聚合物 偶氮二苯羧酸 晶体结构 拓扑 |
| 基金项目: |
| Abstract: A novel Mn coordination polymers, Mn2(ADB)2(DMSO)4·DMSO (H2ADB=4,4′-azodibenzoic acid), has been prepared by solvothermal reaction and characterized by element analysis, IR spectra and single-crystal X-ray diffraction. The crystallographic data shows that the title complex crystallizes in monoclinic space group C2/c. Each Mn(Ⅱ) is six-coordinated to four O atoms from three ADB2- ligands, two oxygen atoms from two DMSO molecule and forms distorted octahedral coordination geometry. The Mn(Ⅱ) dimers by the carboxyl groups of the ADB2- ligands were interlinked together by the different carboxylate coordination modes of ADB2- ligands, to yield scaffolds with 2D network with 4.82 topological structures. CCDC: 745678. |
| Keywords: Mn(Ⅱ) coordination polymer H2ADB crystal structure topology |
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| 韩银锋,郑泽宝,吴仁涛,孙一峰,李小燕,李季坤.二重穿插锰配合物Mn2(ADB)2(DMSO)4DMSO的溶剂热合成和结构研究[J].无机化学学报,2010,26(6):1125-1128. |
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