| 以2，5-二巯基-1，3，4噻二唑(Ⅰ)为桥连配体的二维镉(Ⅱ)配合物的制备与晶体结构(英文) | |||||||
| Preparation and Crystal Structure of a Two-Dimensional Cadmium(Ⅱ) Coordination Polymer Containing Bismuthiol(Ⅰ) as a Bridging Ligand | |||||||
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| 关键词: 镉配合物 水热合成 晶体结构 荧光性质 | |||||||
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| Abstract: The hydrothermal reaction of CdCl2 with 1,3,4-thiadiazole-2,5-dithiol affords one 2D network cadmium(Ⅱ) coordination polymer, [Cd(5-thioxo-4,5-dihydro-1,3,4-thiadiazole-2-thiolate)2]n. The structure was determined by single crystal X-ray diffraction, the crystal belongs to orthorhombic system with space group Pbcn, and a=1.281 6(2) nm, b=1.162 1(2) nm, c=0.784 06(16) nm, V=1.167 7(4) nm3, Z=4. Its fluorescence was measured. CCDC: 689817. | |||||||
| Keywords: cadmium complex hydrothermal reaction crystal structure fluorescence | |||||||
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| 王文祥,赵 红.以2，5-二巯基-1，3，4噻二唑(Ⅰ)为桥连配体的二维镉(Ⅱ)配合物的制备与晶体结构(英文)[J].无机化学学报,2010,26(6):1109-1112. | |||||||
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