| 银(Ⅰ)、锌(Ⅱ)与2，2′-(2-氨基-苯氧基)乙醚配合物的合成及晶体结构 |
| Synthesis and Crystal Structures of Ag(Ⅰ) and Zn(Ⅱ) Complexes Containing 2,2′-(2-amino-phenoxy)-ether Ligand |
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| 摘要: |
| 关键词: 2，2′-(2-氨基-苯氧基)乙醚 配合物 晶体结构 |
| 基金项目: |
| Abstract: The compound 2,2′-(2-amino-phenoxy)-ether[L] was synthesized from the reaction of diethylene glycol with tosyl chloride. AgClO4 and ZnCl2 each react with L to give two complexes [Ag2L2(H2O)(ClO4)2] (1) and [ZnLCl2]n (2) respectively, and characterized by FTIR and single crystal X-ray diffraction. The results of structural analysis indicated that both complexes crystallize in the monoclinic system with space group P21/c. 1 is a dinuclear complex, and 2 forming 1D zigzag chain by Zn(Ⅱ) linking adjacent ligands in turn. When viewed from the top of the chain, the structure of 2 shows the unidimensional tube. CCDC: 748592, 1; 748594, 2. |
| Keywords: 2,2′-(2-amino-phenoxy)-ether complex crystal structure |
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| 朱兴城,丁亚洲,张奇龙,朱必学.银(Ⅰ)、锌(Ⅱ)与2，2′-(2-氨基-苯氧基)乙醚配合物的合成及晶体结构[J].无机化学学报,2010,26(5):926-930. |
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