KMgF3∶Ce3+,Tb3+纳米粒子中Ce3+→Tb3+的发光及能量传递 |
Luminescence and Energy Transfer of Ce3+→Tb3+ in KMgF3∶Ce3+, Tb3+ Nanoparticles |
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摘要: 利用微乳液方法,合成了铈、铽共掺杂的氟镁钾纳米粒子,研究了体系中Ce3+→Tb3+的发光特性以及它们之间的相互作用,结果表明KMgF3∶Ce3+,Tb3+纳米粒子中存在Ce3+→Tb3+的能量传递过程,即Ce3+可以将吸收的能量直接传递给Tb3+离子,使得Tb3+的绿色发光强度大为增加。 |
关键词: KMgF3∶Ce3+, Tb3+ 纳米粒子 能量传递 |
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Abstract: Nanoparticles of KMgF3∶Ce3+, Tb3+ were prepared by microemulsion method. Luminescence properties and interactions between Ce3+ and Tb3+ were studied.The results show that there is an energy transfer process from Ce3+ to Tb3+ in KMgF3∶Ce3+, Tb3+ nanoparticles, namely, Ce3+ ion can directly transfer the absorbed energy to Tb3+ ion, which makes the green luminescence intensity of Tb3+ ion stronger. |
Keywords: KMgF3∶Ce3+, Tb3+ nanoparticles energy transfer |
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摘要点击次数: 1993 |
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张海燕,曹亮军,王琳琨,郭海燕,祁芸芸,闫景辉.KMgF3∶Ce3+,Tb3+纳米粒子中Ce3+→Tb3+的发光及能量传递[J].无机化学学报,2010,26(5):822-826. |
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