| Abstract: Two silver coordination polymer: [Ag2(BPE)(CF3COO)2]n(BPE=trans-1,2-bis (2-pyridyl)ethylene) and {Ag5(CF3COO)5[(CH3)3NCH2COO]}n has been synthesized under mild hydrothermal conditions and characterized by single crystal X-ray diffraction. Compound 1 crystallizes in the Monoclinic space group C2/c, with unit cell parameters, a=2.461 3(2) nm, b=0.778 80(7) nm, c=0.778 80(7) nm, β=116.311(2)°, V=3.684 9(6) nm3, Z=8, R1=0.079 9, wR2=0.169 6; Compound 2 crystallizes in the Monoclinic space group P21/c, with unit cell parameters, a=0.954 96(14) nm, b=1.311 75(18) nm, c=2.306 3(3) nm, β=92.217(3)°, V=2. 886 8(7) nm3, Z=4, R1=0.084 1, wR2=0.224 7. CCDC: 762715, 1; 762716, 2. |
