| 单一手性一价铜配位聚合物：晶体结构，荧光，SHG响应及介电性质(英文) |
| A Homochiral Cu(Ⅰ) Coordination Polymer: Crystal Structure, Luminescent, SHG Response and Dielectric Property |
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| 摘要: |
| 关键词: 手性 一价铜 配位聚合物 荧光 介电 SHG |
| 基金项目: |
| Abstract: Under hydrothermal conditions, homochiral ligand (4aR,8aR)-2,3-di(thiophen-2-yl)-decahydroquinoxaline(DTDCQ) reacted with CuBr to give 1D helical chain complexes [(DTHHQ)CuBr]n (1). Single crystal X-ray determination shows that compound 1 crystallize in chiral space groups P212121 and the experimental result indicated that 1 has SHG (second harmonic generation) active with approximate responses 0.4 times that of urea, Fluorescent analysis showed it exhibits one intense emission band at 377 nm when the exciting radiation was set at 340 nm. Dielectric constant of compound 1 were measured at different frequencies at room temperature. CCDC: 745354. |
| Keywords: chiral Cu(Ⅰ) coordination polymer fluorescence permittivity SHG |
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| 摘要点击次数: 1287 |
| 全文下载次数: 1937 |
| 陈立庄,韩光范,叶恒云,胡宏纹.单一手性一价铜配位聚合物：晶体结构，荧光，SHG响应及介电性质(英文)[J].无机化学学报,2010,26(3):541-545. |
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